研究成果

原著論文 2019年度

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計画班A01 計画班A02 計画班A03 計画班B01 計画班B02
計画班C01
計画班C02
公募A班
公募B班
公募C班
計画班A01
Kato K., Shinoda T., Nagao R., Akimoto S., Suzuki T., Dohmae N., Chen M., Allakhverdiev S. I., Shen J.-R., Akita F., Miyazaki N., Tomo T., “Structural basis for the adaptation and function of chlorophyll f in photosystem I.”, Nat. Comm., 11, 1, 238 (2020)
Kato K., Nagao R., Jiang T.-Y., Ueno Y., Yokono M., Chan S. K., Watanabe M., Ikeuchi M., Shen J.-R., Akimoto S., Miyazaki N., Akita F., “Structure of a cyanobacterial photosystem I tetramer revealed by cryo-electron microscopy”, Nat. Comm., 10, 4929 (2019)
Shen L., Huang Z., Chang S., Wang W., Wang J., Kuang T., Han G., Shen J.-R., Zhang X., “Structure of a C2S2M2N2-type PSII-LHCII supercomplex from the green alga Chlamydomonas reinhardtii.”, Proc. Natl. Acad. Sci. USA, 116, 42, 21246-21255 (2019)
Voloshin R. A., Brady N. G., Zharmukhamedov S. K., Feyziyev Y. M., Huseynova I. M., Najafpour M. M., Shen J.‐R., Veziroglu T. N., Bruce B. D., Allakhverdiev S. I., “Influence of osmolytes on the stability of thylakoid‐based dye‐sensitized solar cells.”, Int. J. Energy Res., 43, 8878-8889 (2019)
Ueno Y., Nagao R., Shen J.-R., Akimoto S., “Spectral properties and excitation relaxation of novel fucoxanthin chlorophyll a/c-binding protein complexes.”, J. Phys. Chem. Lett., 10, 5148-5152 (2019)
Suga M., Akita F., Yamashita K., Nakajima Y., Ueno G., Li H., Yamane T., Hirata K., Umena Y., Yonekura S., Yu L.-J., Murakami H., Nomura T., Kimura T., Kubo M., Baba S., Kumasaka T., Tono K., Yabashi M., Isobe H., Yamaguchi K., Yamamoto M., Ago H., Shen J.-R., “An open-cubane oxyl/oxo mechanism for O=O bond formation in PSII revealed by XFEL”, Science, 366, 334-338 (2019)
Pi X., Zhao S., Wang W., Liu D., Xu C., Han G., Kuang T., Sui S.-F., Shen J.-R., “The pigment-protein network of a diatom photosystem II-light harvesting antenna supercomplex”, Science, 365, eaax4406 (2019)
Nagao R., Kato K., Suzuki T., Ifuku K., Uchiyama I., Kashino Y., Dohmae N., Akimoto S., Shen J.-R., Miyazaki N., Akita F., “Structural basis for energy harvesting and dissipation in a diatom PSII-FCPII”, Nature Plants, 5, 8, 890-901 (2019)
Mousazade Y., M. Najafpour M., Bagheri R., Jagličić Z., Singh J. P., Chae K. H., Song Z., Rodionova M. V., Voloshin R. A., Shen J.-R., Ramakrishna S., Allakhverdiev S. I., “A manganese(II) phthalocyanine under water-oxidation reaction: new findings”, Dalton Trans., 48, 12147-12158 (2019)
Nakamura A., Kang J., Terada R., Kino H., Umena Y., Kawakami K., Shen J.-R., Kamiya N., Tateno M., “Novel mechanism of Cl-dependent proton dislocation in photosystem II (PSII): Hybrid ab initio quantum mechanics/molecular mechanics molecular dynamics simulation”, J. Phys. Soc. Japan, 88, 84802 (2019)
Shoji M., Isobe H., Shen J.-R., Suga M., Akita F., Miyagawa K., Shigeta Y., Yamaguchi K., “Elucidation of the entire Kok cycle for photosynthetic water oxidation by the large-scale quantum mechanics/molecular mechanics calculations: Comparison with the experimental results by the recent serial femtosecond crystallography”, Chem. Phys. Lett., 730, 416-425 (2019)
Nagao R., Yokono M., Ueno Y., Shen J.-R., Akimoto S., “pH-sensing machinery of excitation energy transfer in diatom PSI− FCPI complexes”, J. Phys. Chem. Lett., 10, , 3531-3535 (2019)
Chen J., Chen J., Liu Y., Zheng Y., Zhu Q., Han G., Shen J.-R., “Proton-coupled electron transfer of plastoquinone redox reactions in photosystem II: A pump−probe ultraviolet resonance raman study”, J. Phys. Chem. Lett., 10, 3240−3247 (2019)
Nagao R., Ueno Y., Yokono M., Shen J.-R., Akimoto S., “Effects of excess light energy on excitation-energy dynamics in a pennate diatom Phaeodactylum tricornutum”, Photosyn. Res., 141, 3, 355-365 (2019)
Nagatsuma S., Gotou K., Yamashita T., Yu L.-J., Shen J.-R., Madigan M.T., Kimura Y., Wang-Otomo Z.Y., “Phospholipid distributions in purple phototrophic bacteria and LH1-RC core complexes”, Biochim Biophys Acta Bioenerg., 1860, 6, 461-468 (2019)
Isobe H., Shoji M., Suzuki T., Shen J.-R., Yamaguchi K. (2019), “Spin, valence, and structural isomerism in the S3 state of the oxygen-evolving complex of photosystem II as a manifestation of multimetallic cooperativity”, J. Chem. Theory. Comput., 15, 4, 2375-2391 (2019)
Nagao R., Kagatani K., Ueno Y., Shen J.-R., Akimoto S., “Ultrafast excitation-energy dynamics in diatom photosystem i-antenna complex: A femtosecond fluorescence upconversion study”, J. Phys. Chem. B, 123, 2673-2678 (2019)
Li Z., Qi Y., Wang W., Li D., Li Z., Xiao Y., Han G., Shen J.-R., Li C., “Blocking backward reaction on hydrogen evolution cocatalyst in a photosystem II hybrid Z-scheme water splitting system”, Chin. J. Catal., 40, , 486–494 (2019)
Sipka G., Müller P., Brettel K., Magyar M., Kovács L., Zhu Q., Xiao Y.,, Han G., Lambrev P. H., Shen J.-R., Garab G., “Redox transients of P680 associated with the incremental chlorophyll-a fluorescence yield rises elicited by a series of saturating flashes in diuron-treated Photosystem II core complex of Thermosynechococcus vulcanus”, Physiol. Plant., 166, 22–32 (2019)
Nagao R., Ueno Y., Akita F., Suzuki T., Dohmae N., Akimoto S., Shen J.-R., “Biochemical characterization of photosystem I complexes having different subunit compositions of fucoxanthin chlorophyll a/c-binding proteins in the diatom Chaetoceros gracilis”, Photosyn. Res., 140, 2, 141-149 (2019)
A. Taniguchi, S. Koeda, T. Noji, K. Kawakami, N. Sumito, T. Dewa, S. Itoh, N. Kamiya, T. Mizuno, “Synthesis and characterization of chemically-reactive solubilization surfactants for membrane proteins and preparation of membrane protein hydrogel microfibers”, Colloid and Interf. Sci. Commun., 32, 100199 (2019)
Atsushi Nakamura, Jiyoung Kang, Ryu-ichiro Terada, Hiori Kino, Yasufumi Umena, Keisuke Kawakami, Jian-Ren Shen, Nobuo Kamiya, and Masaru Tateno, “Novel mechanism of Cl-dependent proton dislocation in photosystem II (PSII): Hybrid ab initio quantum mechanics/molecular mechanics molecular dynamics simulation”, JPSJ, 8884802 (2019)
Yuya Takekuma, Haruki Nagakawa, Tomoyasu Noji, Keisuke Kawakami, Rei Furukawa, Mamoru Nango, Nobuo Kamiya and Morio Nagata, “Enhancement of Photocurrent by Integration of an Artificial Light-Harvesting Antenna with a Photosystem I Photovoltaic Device”, ACS Appl. Energy Matel., 2, 3986-3990 (2019)
Haruki Nagakawa, Ayano Takeuchi, Yuya Takekuma, Tomoyasu Noji, Keisuke Kawakami, Nobuo Kamiya, Mamoru Nango, Rei Furukawad and Morio Nagata, “Efficient hydrogen production using photosystem I enhanced by artificial light harvesting dye”, Photochem. Photobiol. Sci., 18, 309-313 (2019)
Shota Akai, Hiroko Ikushiro, Taiki Sawai, Takato Yano, Nobuo Kamiya, and Ikuko Miyahara, “The crystal structure of homoserine dehydrogenase complexed with L-homoserine and NADPH in a closed form”, J. Biochem., 165, 185-195 (2019)
M Suga, F Akita, K Yamashita, Y Nakajima, G Ueno, H Li1, T Yamane, K Hirata, Y Umena, S Yonekura, L-J Yu, H Murakami, T Nomura, T Kimura, M Kubo, S Baba, T Kumasaka, K Tono, M Yabashi, H Isobe, K Yamaguchi, M Yamamoto, H Ago, J-R Shen, “An oxyl/oxo mechanism for oxygen-oxygen coupling in PSII revealed by an x-ray free-electron laser”, 366, 6463, 334-338 (2019)
K Miyagawa, H Isobe, T Kawakami, M Shoji, S Yamanaka, M Okumura, T Nakajima, K Yamaguchi, “Domain-based local pair natural orbital CCSD (T) calculations of fourteen different S2 intermediates for water oxidation in the Kok cycle of OEC of PSII. Re-visit to one LS-two HS model for the S2 state”, Chemical Physics Letters, 734, 136731 (2019)
K Miyagawa, H Isobe, T Kawakami, M Shoji, S Yamanaka, M Okumura, T Nakajima, K Yamaguchi, “Domain-based local pair natural orbital CCSD (T) calculations of six different S1 structures of oxygen evolving complex of photosystem II. Proposal of multi-intermediate models for the S1 state”, Chemical Physics Letters, 732, 136660 (2019)
K Miyagawa, H Isobe, T Kawakami, M Shoji, S Yamanaka, M Okumura, T Nakajima, K Yamaguchi, “Domain-based local pair natural orbital CCSD (T) calculations of strongly correlated electron systems: Examination of dynamic equilibrium models based on multiple intermediates in S1 state of photosystem II”, Molecular Physics (2019)
K Yamaguchi, M Shoji, H Isobe, K Miyagawa, K Nakatani, “Theory of chemical bonds in metalloenzymes XXII: a concerted bond-switching mechanism for the oxygen–oxygen bond formation coupled with one electron transfer for water oxidation in the oxygen-evolving complex of photosystem II”, Molecular Physics, 117, 17, 2320-2354 (2019)
M Shoji, H Isobe, J-R Shen, M Suga, F Akita, K Miyagawa, Y Shigeta, K Yamaguchi, “Elucidation of the entire Kok cycle for photosynthetic water oxidation by the large-scale quantum mechanics/molecular mechanics calculations: Comparison with the experimental results by the recent serial femtosecond crystallography”, Chemical Physics Letters, 730, , 416-425 (2019)
K Yamaguchi, S Yamanaka, H Isobe, M Shoji, K Miyagawa, T Nakajima, T Kawakami, M Okumura, “Theoretical and computational investigations of geometrical, electronic and spin structures of the CaMn4OX (X = 5, 6) cluster in the Kok cycle Si (i = 0–3) of oxygen evolving complex of photosystem II” (2019)

計画班A02
Y. Shimada, T. Kitajima-Ihara, R. Nagao, T. Noguchi, “Role of the O4 channel in photosynthetic water oxidation as revealed by Fourier transform infrared difference and time-resolved infrared analysis of the D1-S169A mutant”, J. Phys. Chem. B, 124, 8, 1470−1480 (2020)
Y. Kato, S. Haniu, Y. Nakajima, F. Akita, J.-R. Shen, T. Noguchi, “FTIR Microspectroscopic analysis of the water oxidation reaction in a single photosystem II microcrystal”, J. Phys. Chem. B, 124, 1, 121-127 (2020)
T. Kitajima-Ihara, T. Suzuki, S. Nakamura, Y. Shimada, R. Nagao, N. Dohmae, T. Noguchi, “Fourier transform infrared and mass spectrometry analyses of a site-directed mutant of D1-Asp170 as a ligand to the water-oxidizing Mn4CaO5 cluster in photosystem II”, Biochim. Biophys. Acta Bioenergetics, 1861, 1, 148086 (2020)
Y. Kato, A. Ohira, R. Nagao, T. Noguchi, “Does the water-oxidizing Mn4CaO5 cluster regulate the redox potential of the primary quinone electron acceptor QA in photosystem II? A study by Fourier transform infrared spectroelectrochemistry”, Biochim. Biophys. Acta Bioenergetics, 1860, 12, 148082 (2019)
H. Takemoto, M. Sugiura, T. Noguchi, “Proton release process during the S2-to-S3 transition of photosynthetic water oxidation as revealed by the pH dependence of kinetics monitored by time-resolved infrared spectroscopy”, Biochemistry, 58, 42, 4276-4283 (2019)
*Boussac, A., Sellés, J., and Sugiura, M., “What can we still learn from the electrochromic band-shifts in Photosystem II?”, Biochim. Biophys. Acta (Bioenergetics), 1861, 148176 (2020)
Takemoto, H., Sugiura, M., and *Noguchi, T., “Proton release process during the S2-to-S3 transition of photosynthetic water oxidation as revealed by the pH dependence of kinetics monitored by time-resolved infrared spectroscopy”, Biochemistry, 58, 4276-4283 (2020)
Motomura, T., Zuccarello, L., Sétif, P., Boussac, A., Umena, Y., Lemaire, D., Tripathy, J.N., Sugiura, M., Hienerwadel, R., *Shen, J.R., and *Berthomieu, C., “An alternative plant-like cyanobacterial ferredoxin with unprecedented structural and functional properties”, Biochim. Biophys. Acta (Bioenergetics), 1860, 14804 (2019)

計画班A03
S. Shoji, Y. Nomura, H. Tamiaki, “Covalent heterodyads of synthetic chlorophyll derivatives linked with linear rigid substituents at the 20-positions constructing photoexcited energy transfer systems”, Tetrahedron, 76, 17, 131130 (2020)
T. Takahashi, S. Ogasawara, Y. Shinozaki, H. Tamiaki, “Synthesis of cationic pyridinium–chlorophyll conjugates with various counter anions and effects of the anions on their photophysical properties”, Bull. Chem. Soc. Jpn., 93, 4, 467–476 (2020)
S. Matsubara, H. Tamiaki, “Photoactivated supramolecular assembly using "caged chlorophyll" for the generation of nanotubular self-aggregates having controlling lengths”, ACS Applied Nano Materials, 3, 2, 1841–1847 (2020)
H. Tamiaki, K. Fukai, S. Nakamura, “Intramolecular interaction of synthetic chlorophyll heterodyads with different π-skeletons”, Photochem. Photobiol. Sci., 19, 3, 332–34 (2020)
Y. Kawamoto, Y. Kinoshita, H. Tamiaki, “Synthesis of tin(IV) complexes of chlorophyll-a derivatives with two halides as axial ligands and their optical properties in solution”, Tetrahedron, 76, 8, 130948 (2020)
M. Doi, H. Tamiaki, “Synthesis of sedimentary porphyrin-like chlorophyll-a derivatives lacking the 3-substituent”, Chem. Lett., 49, 3, 287–289 (2020)
Ogasawara, Y. Egami, M. Hirose, H. Tamiaki, “Synthesis of chlorophyll-a homologs by C132-substitutions and their physico- and biochemical properties”, Bioorg. Chem., 94, 103383 (2020)
S. Sasaki, S. Duan, W. Hu, X.-F. Wang, H. Tamiaki, “Evaluation of covalently linked (bacterio)chlorophyll-fullerenes as components for organic solar cells”, J. Porphyrins Phthalocyanines, 24, 200–210 (2020)
D. Funakoshi, Y. Nomura, S. Shoji, H. Tamiaki, “Synthetic substituted boronates of dihydroxy-bacteriochlorin absorbing and emitting far-red to near-infrared light as bacteriopheophytin-a analogs”, Dyes Pigments, 175, 108155 (2020)
A. Katayama, H. Tamiaki, “Synthesis of zinc bacteriochlorophyll-d analogs bearing an alkoxyimino group at the 131-position and their self-aggregation in an aqueous micelle solution”, Tetrahedron Lett., 61, 3, 151386 (2020)
T. Nakano, H. Tamiaki, “Palladium-catalyzed acylation of terminal alkynes toward 3-yneone-linked chlorophyll-a derivatives”, J. Org. Chem., 84, 24, 16116–16123 (2019)
W. Zhao, L. Wang, L. Pan, S. Duan, N. Tamai, S. Sasaki, H. Tamiaki, Y. Sanehira, Y. Wei, G. Chen, X.-F. Wang, “Charge transfer dynamics of chlorophyll-based biosolar cells”, Phys. Chem. Chem. Phys., 21, 40, 22563–22568 (2019)
S. Shoji, T. Ogawa, S. Matsubara, H. Tamiaki, “Bioinspired supramolecular nanosheet of zinc chlorophyll assembly”, Sci. Rep., 9, 0, 14006 (2019)
S. Ikeyama, S. Hizume, T. Takahashi, S. Ogasawara, Y. Amao, H. Tamiaki, “Visible-light driven hydrogen production using chlorophyll derivatives conjugated a viologen moiety in the presence of platinum nanoparticles”, Photochem. Photobiol. Sci., 18, 11, 2673–2681 (2019)
T. Takahashi, S. Ogasawara, Y. Shinozaki, H. Tamiaki, “Synthesis of cationic pyridinium-(bacterio)chlorophyll conjugates bearing a bacteriochlorin, chlorin or porphyrin -skeleton and their photophysical and electrochemical properties”, Eur. J. Org. Chem., 37, 6333–6340 (2019)
S. Duan, Q. Zhou, C. Dall'Agnese, G. Chen, X.-F. Wang, H. Tamiaki, K. Sakai, T. Ikeuchi, S. Sasaki, “Organic solar cells based on aggregate of synthetic chlorophyll derivative with over 5% efficiency”, Solar RRL, 3, 12, 1900203 (2019)
N. Li, C. Dall'Agnese, W. Zhao, S. Duan, G. Chen, S. Sasaki, H. Tamiaki, Y. Sanehira, T. Miyasaka, X.-F. Wang, “Bilayer chlorophyll derivatives as efficient hole-transporting layers for perovskite solar cells”, Mater. Chem. Front., 3, 11, 2357–2362 (2019)
M. Doi, H. Tamiaki, “Synthesis of a chlorophyll-a derivative fused with an additional exo-five-membered ring and its optical properties”, Tetrahedron Lett., 60, 33, 150934 (2019)
H. Watanabe, S. Nakamura, H. Tamiaki, “Supramolecular complex of chlorophyll-a derivative with N-protected histidine through two-point binding”, Chem. Lett., 48, 8, 982–984 (2019)
M. Teramura, Y. Tsukatani, J. Harada, M. Hirose, H. Tamiaki, “Stereoselective C3-substituent modification and substrate channeling by oxidoreductase BchC in bacteriochlorophyll a biosynthesis”, FEBS Lett., 593, 8, 799–809 (2019)
T. Takahashi, S. Ogasawara, S. Echizen, Y. Shinozaki, H. Tamiaki, “C31-Selective substitution of cationic N-heteroaromatic groups into a 3-vinylated chlorophyll-a derivative”, Org. Biomol. Chem., 17, 22, 5490–5495 (2019)
Y. Fujiwara, H. Tamiaki, “Stereoselective self-aggregation of synthetic zinc 31-epimeric bacteriochlorophyll-d analogs possessing a methylene group at the 132-position as models of green photosynthetic bacterial chlorosomes”, Photochem. Photobiol. Sci., 18, 5, 1218–1227 (2019)
Y. Kashiyama, A. Yokoyama, T. Shiratori, S. Hess, F. Not, C. Bachy, A. Gutiérrez-Rodríguez, M. Wang, M. Chen, Y. Gong, K. Seto, M. Kagami, Y. Hamamoto, D. Honda, T. Umetani, A. Shihongi, M. Kayama, T. Matsuda, J. Taira, A. Yabuki, M. Tsuchiya, Y. Hirakawa, A. Kawaguchi, M. Nomura, A. Nakamura, N. Namba, M. Matsumoto, T. Tanaka, T. Yoshino, R. Higuchi, A. Yamamoto, T. Maruyama, A. Yamaguchi, A. Uzuka, S. Miyagishima, J. Kawahara, T. Suzaki, M. Nakazawa, T. Ishikawa, M. Maruyama, G. Tanifuji, M. Kawachi, Y. Kinoshita, and H. Tamiaki, “Taming chlorophylls by early eukaryotes underpinned algal interactions and the diversification of the eukaryotes on the oxygenated Earth”, ISME J., 13, 8, 1899–1910 (2019)
Y. Tsukatani, Y. Hirose, J. Harada, C. Yonekawa, H. Tamiaki, “Unusual features in the photosynthetic machinery of Halorhodospira halochloris revealed by complete genome sequencing”, Photosynth. Res., 140, 3, 311–319 (2019)
K. Ohashi, Y. Kinoshita, H. Tamiaki, “Synthesis of chalcone-type chlorophyll derivatives possessing a bacteriochlorin, chlorin or porphyrin π-system and their optical properties”, Photochem. Photobiol, 95, 3, 755–761 (2019)

計画班B01
Kota Horiuchi, Chiasa Uragami, Taiki Inoue, Nao Yukihira, Daisuke Kosumi, Hideki Hashimoto, “Analysis on the excited state properties of cis-β-apo-8'-caortenal using femtosecond time-resolved absorption spectroscopy”, Carotenoid Science, 23, 24 (2019)
Taiki Inoue, Shota Seto, Tomoko Horibe, Kota Horiuchi, Chiasa Uragami, Hideki Hashimoto, “Generation of Geometric Isomers of β-Apo-8'-Carotenal and Investigation of Their Optical Properties Using Stark Spectroscopy”, Carotenoid Science, 23, 32 (2019)
Masayuki Yoshizawa, Ren Sato, Nao Yukihira, Chiasa Uragami, Hideki Hashimoto, “Efficient Energy Transfer in Light-Harvesting Function from an Intra-Molecular Charge Transfer State of Fucoxanthin in Reconstituted LH1 Complex”, Carotenoid Science, 23, 47 (2019)
Daisuke Kosumi, Toshiyuki Kusumoto, and Hideki Hashimoto, “Anomalous Optical Properties of Artificial Short-Polyene Carotenoid”, Carotenoid Science, 23, 9 (2019)
Masazumi Fujiwara, Ryuta Tsukahara, Yoshihiko Sera, Hiroshi Yukawa, Yoshinobu Baba, Shinichi Shikata, Hideki Hashimoto, “Monitoring spin coherence of single nitrogen-vacancy centers in nanodiamonds during pH changes in aqueous buffer solutions”, RSC Advances, 9, 12606 (2019)
Yoshinao Shinozaki, Chiasa Uragami, Hideki Hashimoto, Hitoshi Tamiaki, “A Synthetic Chlorophyll Dimer Appending Fullerene: Effect of Chlorophyll Pairing on (Photo)redox Properties”, Chemistry - A European Journal (2020)
Ryo Miyasato, Masazumi Fujiwara, Chiasa Uragami, Haruyuki Sato, Toshihiro, Yano, Hideki Hashimoto, “Operando time-resolved diffuse reflection spectroscopy: the origins of photocatalytic water-oxidation activity of bismuth vanadate”, Journal of Photochemistry and Photobiology A: Chemistry, (2020)
N. T. Phuc, A. Ishizaki, and P. Q. Trung, “Controlling the electron-transfer-like reaction rate through molecular-vibration polaritons in the ultrastrong coupling regime”, Sceintific Reports (in press), (2020)
A. Ishizaki, “Prerequisites for Relevant Spectral Density and Convergence of Reduced Density Matrices at Low Temperatures”, J. Phys. Soc. Jpn, 89, 1, 15001 (2020)
N. T. Phuc and A. Ishizaki, “Precise determination of excitation energies in condensed-phase molecular systems based on exciton-polariton measurements”, Physical Review Research, 1, 33019 (2019)

計画班B02
T. Kanazawa, K. Kato, R. Yamaguchi, T. Uchiyama, D. Lu, S. Nozawa, A. Yamakata, Y. Uchimoto, K. Maeda, “Cobalt Aluminate Spinel as a Cocatalyst for Photocatalytic Oxidation of Water: Significant Hole-Trapping Effect”, ACS Catal., 4960-4966 (2020)
T. Kanazawa, M. Eguchi, S. Nozawa, K. Maeda, “Improved Electrochemical Water Oxidation over Chromium-Substituted Cobalt Aluminate Spinels”, Bull. Chem. Soc. Jpn., 93, 13-19 (2020)
A. Koide, Y. Uemura, D. Kido, Y. Wakisaka, S. Takakusagi, B. Ohtani, Y. Niwa, S. Nozawa, K. Ichiyanagi, R. Fukaya, S. Adachi, T. Katayama, T. Togashi, S. Owada, M. Yabashi, Y. Yamamoto, M. Katayama, K. Hatada, T. Yokoyama, and K. Asakura, “Photoinduced anisotropic distortion as the electron trapping site of tungsten trioxide by ultrafast W L1-edge X-ray absorption spectroscopy with full potential multiple scattering calculations”, Phys. Chem. Chem. Phys., 22, 2615-2621 (2020)
S. Takagi, K. Ichiyanagi, A. Kyono, S. Nozawa, N. Kawai, R. Fukaya, N. Funamori and S. Adachi, “Development of shock-dynamics study with synchrotron-based time-resolved X-ray diffraction using an Nd:glass laser system”, J. Synchrotron Rad., 27, 371-377 (2020)
K. Ichiyanagi, S. Takagi, N. Kawai, R. Fukaya, S. Nozawa, K. G. Nakamura, K-D. Liss, M. Kimura, S. Adachi, “Microstructural deformation process of shockcompressed polycrystalline aluminum”, Sci. Reports, 9, 7604 (2019)
M. Hada, K. Miyata, S. Ohmura, Y. Arashida, K. Ichiyanagi, I. Katayama, T. Suzuki, W. Chen, S. Mizote, T. Sawa, T. Yokoya, T. Seki, J. Matsuo, T. Tokunaga, C. Itoh, K. Tsuruta, R. Fukaya, S. Nozawa, S. Adachi, J. Takeda, K. Onda, S. Koshihara, Y. Hayashi, Y. Nishina, “Selective Reduction Mechanism of Graphene Oxide Driven by the Photon Mode versus the Thermal Mode”, ACS Nano, 13, 10103-10112 (2019)
K. Shibata, K. Kato, C. Tsounis, T. Kanazawa, D. Lu, S. Nozawa, A. Yamakata, O. Ishitani, K. Maeda, “Synthesis of Copolymerized Carbon Nitride Nanosheets from Urea and 2-Aminobenzonitrile for Enhanced Visible Light CO2 Reduction with a Ruthenium(II) Complex Catalyst”, Solar PRL, 1900461 (2019)
T.Katayama, S. Nozawa, Y. Umena, S. Lee, T. Togashi, S. Owada, and M. Yabashi, “A versatile experimental system for tracking ultrafast chemical reactions with X-ray free-electron lasers”, Structural Dynamics, 6, 54302 (2019)
T. Katayama, T. Northey, W. Gawelda, C. J. Milne, G. Vankó, F. A. Lima, R. Bohinc, Z. Németh, S. Nozawa, T. Sato, D. Khakhulin, J. Szlachetko, T. Togashi, S. Owada, S. Adachi, C. Bressler, M. Yabashi, and T. J .Penfold, “Tracking multiple components of a nuclear wavepacket in photexcited Cu(I)-phenanthroline complex using ultrafast X-ray spectroscopy”, Nature Comm., 10, 3606 (2019)
T. Ishizuka, T. Kogawa, M. Makino, Y. Shiota, K. Ohara, H. Kotani, S. Nozawa, S. Adachi, K. Yamaguchi, K. Yoshizawa and T. Kojima, “Formation of a Ruthenium(V)-Imido Complex and the Reactivity in Substrate Oxidation in Water through the Nitrogen Non-Rebound Mechanism”, Inorg. Chem., 58, 12815-12824 (2019)
Y. Kitamoto, Z. Pan, D. D. Prabhu, A. Isobe, T. Ohba, N. Shimizu, H. Takagi, R. Haruki, S. Adachi and S. Yagai, “One-shot preparation of topologically chimeric nanofibers via a gradient supramolecular copolymerization”, Nature Comm., 10, 12815-12824 (2019)
A. Suzuki, K. Aratsu, S. Datta, N. Shimizu, H. Takagi, R. Haruki, S. Adachi, M. Hollamby, F. Silly and S. Yagai, “Topological Impact on the Kinetic Stability of Supramolecular Polymers”, J. Am. Chem. Soc., 141, 13196-13202 (2019)
T. Kajitani, K. Motokawa, A. Kosaka, Y. Shoji, R. Haruki, D. Hashizume, T. Hikima, M. Takata, K. Yazawa, K. Morishima, M. Shibayama, T. Fukushima, “Chiral crystal-like droplets displaying unidirectional rotational sliding”, Nature Materials, 18, 266-272 (2019)
H. Matsukawa, M. Yoshida, T. Tsunenari, S. Nozawa, A. Sato-Tomita, Y. Maegawa, S. Inagaki, A. Kobayashi, M. Kato, “Fast and stable vapochromic response induced through nanocrystal formation of a luminescent platinum(II) complex on periodic mesoporous organosilica”, Scientific Reports, 9, 15151 (2019)
K. Watanabe, A. Iwase, S. Nozawa, S. Adachi, A. Kudo, “Effects of Coapplication of Rh-Doping and Ag-Substitution on the Band Structure of Li2TiO3 and the Photocatalytic Property”, ACS Sustainable Chem. Eng., 7, 9881-9887 (2019)
S. Park, J. Choi, H. Ki, K. H. Kim, K. Y. Oang, H. Roh, J. Kim, S. Nozawa, T. Sato, S. Adachi, J. Kim, H. Ihee, “Fate of transient isomer of CH2I2: Mechanism and origin of ionic photoproducts formation unveiled by time-resolved x-ray liquidography”, J. Chem. Phys., 150, 224201 (2019)
K. Mishima, M. Kaneko, J-W. Song, H. Kawai, K. Yamashita, K. Hirao, “Application of Accelerated Long-range Corrected Exchange Functional [LC-DFT(2Gau)] to Periodic Boundary”, Journal of Chemical Physics, 152, 104105 (2020)
J. Nagakubo, T. Nishihashi, K. Mishima, K.Yamashita, “First-principles approach to the first step of metal–phosphine bond formation to synthesize alloyed quantum dots using dissimilar metal precursor”, Chem. Phys., 528, 110512 (2020)
K. Mishima, K. Yamashita, “Importance of Side-Chains on Molecular Characteristics of Interacting Organic Molecules”, ACS Omega, 4, 10396-10404 (2019)
E. Kawashima, M. Fujii, K. Yamashita, “Entropy Promotes Charge Separation in Bulk Heterojunction Organic Photovoltaics”, J. Photochemistry & Photobiology A: Chemistry, 382, 11875 (2019)

計画班C01
Akinobu Nakada, Hajime Suzuki, Junie Jhon M. Vequizo, Kanta Ogawa, Masanobu Higashi, Akinori Saeki, Akira Yamakata, Hiroshi Kageyama*, Ryu Abe*, “Fe/Ru Oxide as a Versatile and Effective Cocatalyst for Boosting Z‑Scheme Water-Splitting: Suppressing Undesirable Backward Electron Transfer”, ACS Appl. Mater. Interfaces, 11, , 45606-45611 (2019)
Christopher D. Windle, Hiromu Kumagai, Masanobu Higashi, Romain Brisse, Sebastian Bold, Bruno Jousselme, Murielle Chavarot-Kerlidou, Kazuhiko Maeda, Ryu Abe,* Osamu Ishitani,* and Vincent Artero*, “Earth-Abundant Molecular Z‑Scheme Photoelectrochemical Cell for Overall Water-Splitting”, J. Am. Chem. Soc., 141, 9593-9602 (2019)
Akinobu Nakada, Masanobu Higashi, Takuma Kimura, Hajime Suzuki, Daichi Kato, Hiroyuki Okajima, Takafumi Yamamoto, Akinori Saeki, Hiroshi Kageyama,* Ryu Abe*, “Band Engineering of Double-Layered Sillén-Aurivillius Perovskite Oxychlorides for Visible-Light-Driven Water Splitting”, Chem. Mater, 31, 3419-3429 (2019)
Yukari Iwase, Osamu Tomita, Masanobu Higashi, Akinobu Nakada, Ryu Abe*, “Effective strategy for enhancing Z-scheme water splitting with the IO3−/I− redox mediator by using a visible light responsive TaON photocatalyst co-loaded with independently optimized two different cocatalysts”, Sustainable Energy and Fuels, 3, 1501-1508 (2019)
Fazalurahman Kuttassery, Siby Mathew, Hiroshi Tachibana, Haruo Inoue*, “How One-photon can Induce Water Splitting into Hydrogen peroxide and Hydrogen by Aluminum Porphyrins? Rationale of the Thermodynamics”, Sustainable Energy & Fuels, 4, 1945-1953 (2020)
Vivek Ramakrishnan, Yu Nabetani, Daisuke Yamamoto, Hiroshi Tachibana, Haruo Inoue*, “Heat trapping in a nano-layered microenvironment: Estimation of temperature by thermal sensing molecules”, Phys. Chem. Chem. Phys., 22, 7201-7209 (2020)
Syed Zahid Hassan, Yu Nabetani, Ayaka Matsumoto, Tsutomu Shiragami, Zhiwei Tong, Hiroshi Tachibana, Haruo Inoue*, “Synthesis of a photo-responsive single-walled nanoscroll and its photo-reactivity in a nano-layered microenvironment”, Phys. Chem. Chem. Phys., 21, 21738-21745 (2019)
Fazalurahman Kuttassery, Shogo Sagawa, Siby Mathew, Yu Nabetani, Akihide Iwase, Akihiko Kudo, Hiroshi Tachibana, Haruo Inoue*, “Water Splitting on Aluminum Porphyrins to form hydrogen and hydrogen peroxide by One-photon of Visible light”, ACS Appl. Energy Mater., 2, 8045-8051 (2019)
Yugo Miseki, Kazuhiro Sayama, “Photocatalytic Water Splitting for Solar Hydrogen Production Using the Carbonate Effect and the Z‐Scheme Reaction”, Advanced Energy Materials, 9, 23, 1801294-1801306 (2019)
Yuta Miyase, Shoji Iguchi, Yugo Miseki, Takahiro Gunji, Kazuhiro Sayama, “Electrochemical H2O2 Production and Accumulation from H2O by Composite Effect of Al2O3 and BiVO4”, JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 166, 13, H644-H649 (2019)
Zeai Huang, Yugo Miseki, Kazuhiro Sayama, “Solar-light-driven photocatalytic production of peroxydisulfate over noble-metal loaded WO3”, CHEMICAL COMMUNICATIONS, 55, 26, 3813 - 3816 (2019)
Yugo Miseki, Kazuhiro Sayama, “Photocatalytic water splitting employing a [Fe(CN)(6)](3-/4-) redox mediator under visible light”, Catalysis Science & Technology, 9, 8, 2019-2024 (2019)
舘野 拓之、佐山 和弘, “光電気化学的手法に基づく酸化的物質変換反応”, ペトロテック, 43, 3, 162-166 (2020)
佐山和弘, “人工光合成からPower-to-X’の実現へ”, 鉱山, 73, 1, 23-36 (2020)
佐山和弘, “太陽エネルギーによる水素と有用化学品製造 -人工光合成から実用化を目指したPower-to-X’へ-”, 化学工学, 83, 11, 670-672 (2019)
佐山和弘, “再生エネルギー電力の自立化のための水素と有用化学品製造”, 会報光触媒, 59, 7, 4ー9 (2019)
Yugo Miseki, Kana Fujita, Shoji Iguchi, Osamu Kitao, Takahiro Gunji, Kazuhiro Sayama, “In-Fe mixed oxide as an oxygen-evolution photocatalyst for visible-light-driven Z-scheme water splitting”, Sustainable Energy & Fuels, in press (2020)
Kojiro Fuku, Ryosuke Takioka, Kazushi Iwamur, Masanobu Todoroki, Kazuhiro Sayama, Naoki Ikenaga, “Photocatalytic H2O2 production from O2 under visible light irradiation over phosphate ion-coated Pd nanoparticles-supported BiVO4”, Applied Catalysis B: Environmental, in press (2020)
Yuta Miyase, Yugo Miseki, Takahiro Gunji, Kazuhiro Sayama, “Efficient H2O2 production via H2O oxidation on an anode modified with Sb-containing mixed metal oxides”, ChemElecChem, in press (2020)
M. Hirahara, H. Goto, R. Yamamoto, M. Yagi, and Y. Umemura, “Photoisomerization and thermal isomerization of ruthenium aqua complexes with chloro-substituted asymmetric bidentate ligands”, RSC Adv., 9, 4, 2002-2010 (2019)
S. Watabe, Y. Tanahashi, M. Hirahara, H. Yamazaki, K. Takahashi, E. A. Mohamed, Y. Tsubonouchi, Z. N. Zahran, K. Saito, T. Yui, M. Yagi, “Critical Hammett electron-donating ability of substituent groups for efficient water oxidation catalysis by mononuclear ruthenium aquo complexes”, Inorg. Chem., 58, 19, 12716-12723 (2019)
D. Chandra, T. Sato, N. Abe, K. Saito, T. Yui, M. Yagi, “Facile and sustainable fabrication of transparent mesoporous IrOx films formed by nanoparticles assembly for efficient electrocatalytic water oxidation”, Sustainable Energy Fuels, 3, 12, 3489-3497 (2019)
D. Chandra, L. Dong, T. Sato, Y. Tanahashi, T. Togashi, M. Ishizaki, M. Kurihara, E. A. Mohamed, Y. Tsubonouchi, Z. N. Zahran, K. Saito, T. Yui, M. Yagi, “Characterization and mechanism of efficient visible-light-driven water oxidation on an in situ N2-intercalated WO3 nanorod photoanode”, ACS Sustainable Chem. Eng., 7, 21, 17896-17906 (2019)
Y. Tsubonouchi, J. Honta, T. Sato, E. A. Mohamed, Z. N. Zahran, K. Saito, T. Yui, M. Yagi, “Multi-potential-step chronocoulospectrometry for electrocatalytic water oxidation by a mononuclear ruthenium aquo complex immobilized on a mesoporous ITO electrode”, Dalton Trans., 49, 5, 1416-1423 (2019)
D. Chandra, T. Sato, Y. Tanahashi, R. Takeuchi, M. Yagi,, “Facile fabrication and nanostructure control of mesoporous iridium oxide films for efficient electrocatalytic water oxidation”, Energy, 173, 278-289 (2019)
Z. N. Zahran, Y. Tsubonouchi, E. A. Mohamed, M. Yagi, “Recent advances in the development of molecular catalyst-based anodes for water oxidation toward artificial photosynthesis”, ChemSusChem, 12, 9, 1775-1793 (2019)

計画班C02
K. Watanabe, A. Iwase, and *A. Kudo, “Solar water splitting over Rh0.5Cr1.5O3-loaded AgTaO3 of a valence-band-controlled metal oxide photocatalyst”, Chem. Sci, 11, 2330 –2334 (2020)
Z. Xie, H. L. Tan, X. Wen, Y. Suzuki, A. Iwase, A. Kudo, R. Amal, J. Scott, and *Y. H. Ng, “The Importance of the Interfacial Contact: Is Reduced Graphene Oxide Always an Enhancer in Photo(Electro)Catalytic Water Oxidation?”, ACS Appl. Mater. Interfaces, 11, 23125−23134 (2019)
F. Kuttassery, S. Sagawa, S. Mathew, Y. Nabetani, A. Iwase, A. Kudo, H. Tachibana, and *H. Inoue, “Water Splitting on Aluminum Porphyrins To Form Hydrogen and Hydrogen Peroxide by One Photon of Visible Light”, ACS Appl.Energy Mater., 2, 8045-8051 (2019)
*A. Iwase, Y. Udagawa, S. Yoshino, Y. H. Ng, R. Amal, and *A. Kudo, “Solar Water Splitting under Neutral Conditions Using Z‐Scheme Systems with Mo‐Doped BiVO4 as an O2‐Evolving Photocatalyst”, Energy Technology, 7, 1900358 (1-6) (2019)
W. Kurashige, R. Hayashi, K. Wakamatsu, Y. Kataoka, S. Hossain, A. Iwase, A. Kudo, S. Yamazoe, and *Y. Negishi, “Atomic-Level Understanding of Effect of Heteroatom Doping of the Cocatalyst on Water-Splitting Activity in AuPd or AuPt Alloy Cluster-Loaded BaLa4Ti4O15”, ACS Appl.Energy Mater., 2, 4175-4187 (2019)
K. Watanabe, A. Iwase, S. Nozawa, S. Adachi, and *A. Kudo, “Effects of Coapplication of Rh-Doping and Ag-Substitution on the Band Structure of Li2TiO3 and the Photocatalytic Property”, ACS Sustainable Chem. Eng., 7, 9881-9887 (2019)
岩瀬顕秀,*工藤昭彦, “可視光水分解および二酸化炭素還元を目指したZスキーム型光触媒の開発”, セラミックス, 3-6 (2019)
吉野隼矢,岩瀬顕秀,*工藤昭彦, “粉末半導体光触媒を用いる人工光合成型二酸化炭素還元”, 電気化学, 87,8-13 (2019)
David C. Fabry, Hiroki Koizumi, Debashis Ghosh, Yasuomi Yamazaki, Hiroyuki Takeda, Yusuke Tamaki and Osamu Ishitani, “A Ru(II) - Mn(I) Supermolecular Photocatalyst for CO2 Reduction”, Organometallics, in publication (2020)
Bing Ma, Gui Chen, Claire Fave, Lingjing Chen, Ryo Kuriki, Kazuhiko Maeda, Osamu Ishitani, Tai-Chu Lau, julien Bonin and Marc Robert, “Efficient Visible-Light Driven CO2 Reduction by a Cobalt Molecular Catalyst Covalently Linked to Mesoporous Carbon Nitride”, J. Am. Chem. Soc., 142, 13, 6188-6195 (2020)
Ambra M Cancelliere, Fausto Puntoriero, Scolastica Serroni, Sebastiano Campagna, Yusuke Tamaki, Daiki Saito and Osamu Ishitani, “Efficient Trinuclear Ru(II)-Re(I) Supremolecular Photocatalysts for CO2 Reduction based on a New Tris-Chelating Bridging Ligand Build”, Chem. Sci., 11,1556-1563 (2020)
Akinari Umemoto, Yasuomi Yamazaki, Daiki Saito, Yusuke Tamaki and Osamu Ishitani, “Syntesis of a Novel Re(I)-Ru(II)-Re(I) Trinuclear Complex as an Effective Photocatalyst for CO2 Reduction”, Bull. Chem. Soc. Jpn., 93, 127-137 (2020)
Yusuke Tamaki, Kazuma Tokuda, Yasuomi Yamazaki, Daiki Saito, Yutaro Ueda and Osamu Ishitani, “Ruthenium picolinate complex as a redox photosensitizer with wide-band absorption”, Front. Chem., 7, Article 327 (2019)
Yasuomi Yamazaki, Kei Ohkubo, Daiki Saito, Taiki Yatsu, Yusuke Tamaki, Seiichi Tanaka, Kazuhide Koike, Ken Onda and Osamu Ishitani, “Kinetics and Mechanism of Intermolecular Electron Transfer in Ru(II) - Re(I) Supermolecular CO2- Reduction Photocatalysts: Effects of Bridgeng Ligands”, Inorg. Chem., 58, 11480 -11492 (2019)

公募A班
Nagatsuma, S., Gotou, K., Yamashita, T., Yu, L.-J., Shen, J.-R., Madigan, M. T., Kimura, Y. & Wang-Otomo, Z.-Y.*, “Phospholipid distributions in purple phototrophic bacteria and LH1-RC core complexes”, Biochim. Biophys. Acta –Bioenergetics, 1860, 461-468 (2019)
Chen, J.-H., Yu, L.-J., Boussac, A., Wang-Otomo, Z.-Y. Kuang, T. & Shen, J.-R.*, “Properties and structure of a low-potential, penta-heme cytochrome c552 from a thermophilic purple sulfur photosynthetic bacterium Thermochromatium tepidum”, Photosynth. Res., 139, 281-293 (2019)
K Miyagawa, H Isobe, T Kawakami, M Shoji, S Yamanaka, M Okumura, T Nakajima, K Yamaguchi, “Domain-based local pair natural orbital CCSD (T) calculations of fourteen different S2 intermediates for water oxidation in the Kok cycle of OEC of PSII. Re-visit to one LS-two HS model for the S2 state”, Chemical Physics Letters, 734, 136731 (2019)
K Miyagawa, H Isobe, T Kawakami, M Shoji, S Yamanaka, M Okumura, T Nakajima, K Yamaguchi, “Domain-based local pair natural orbital CCSD (T) calculations of six different S1 structures of oxygen evolving complex of photosystem II. Proposal of multi-intermediate models for the S1 state”, Chemical Physics Letters, 732, 136660 (2019)
K Miyagawa, H Isobe, T Kawakami, M Shoji, S Yamanaka, M Okumura, T Nakajima, K Yamaguchi, “Domain-based local pair natural orbital CCSD (T) calculations of strongly correlated electron systems: Examination of dynamic equilibrium models based on multiple intermediates in S1 state of photosystem II”, Molecular Physics (2019)
K Yamaguchi, M Shoji, H Isobe, K Miyagawa, K Nakatani, “Theory of chemical bonds in metalloenzymes XXII: a concerted bond-switching mechanism for the oxygen–oxygen bond formation coupled with one electron transfer for water oxidation in the oxygen-evolving complex of photosystem II”, Molecular Physics, 117, 17, 2320-2354 (2019)
M Shoji, H Isobe, J-R Shen, M Suga, F Akita, K Miyagawa, Y Shigeta, K Yamaguchi, “Elucidation of the entire Kok cycle for photosynthetic water oxidation by the large-scale quantum mechanics/molecular mechanics calculations: Comparison with the experimental results by the recent serial femtosecond crystallography”, Chemical Physics Letters, 730, 416-425 (2019)
K Yamaguchi, S Yamanaka, H Isobe, M Shoji, K Miyagawa, T Nakajima, T Kawakami, M Okumura, “Theoretical and computational investigations of geometrical, electronic and spin structures of the CaMn4OX (X = 5, 6) cluster in the Kok cycle Si (i = 0–3) of oxygen evolving complex of photosystem II”, (2019)
Manoj Mandal, Keisuke Kawashima, Keisuke Saito, *Hiroshi Ishikita, “Redox potential of the oxygen-evolving complex in the electron transfer cascade of photosystem II”, J. Phys. Chem. Lett., 11, 249-255 (2020)
Keiichi Kojima, Tetsuya Ueta, Tomoyasu Noji, Keisuke Saito, Kanae Kanehara, Susumu Yoshizawa, Hiroshi Ishikita, *Yuki Sudo, “Vectorial proton transport mechanism of RxR, a phylogenetically distinct and thermally stable microbial rhodopsin”, Sci. Rep., 10, , 282 (2020)
*Hiroyuki Tamura, Koki Azumaya, Hiroshi Ishikita, “Long-range exciton diffusion via singlet revival mechanism”, J. Phys. Chem. Lett., 10, 7623-7628 (2019)
Keisuke Saito, *Hiroshi Ishikita, “Mechanism of protonation of the over-reduced Mn4CaO5 cluster in photosystem II”, Biochim. Biophys. Acta (Bioenergetics), 1860, 148059 (2019)
Y. Yoneda, A. Goto, N. Takeda, H. Harada, M. Kondo, H. Miyasaka, Y. Nagasawa, T. Dewa, “Ultrafast Photodynamics and Quantitative Evaluation of Biohybrid Photosynthetic Antenna and Reaction Center Complexes Generating Photocurrent”, J. Phys. Chem. C (2020)
Y. Yoneda, D. Kato, M. Kondo, K. V. P. Nagashima, H. Miyasaka, Y. Nagasawa, T. Dewa, “Sequential Energy Transfer Driven by Monoexponential Dynamics in a Biohybrid Light–Harvesting Complex 2 (LH2)”, Photosynth. Res., 143, 115-128 (2020)
Tsubasa Hatanaka, Hinano Kusunose, Hiroyuki Kawaguchi, Yasuhiro Funahashi, “Dinitrogen Activation by a Heterometallic VFe Complex Derived from 1,1'-Bis(arylamido)vanadocene”, Eur. J. Inorg. Chem., 1449–1455 (2020)
Bekzhan D. Kossalbayev, Tatsuya Tomo, Bolatkhan K.Zayadan, Asemgul K.Sadvakasova, Kenzhegul Bolatkhan, Saleh Alwasel, Suleyman I. Allakhverdiev, “Determination of the potential of cyanobacterial strains for hydrogen production”, International Journal of Hydrogen Energy, 45, 4, 2627-2639 (2020)
Koji Kato, Toshiyuki Shinoda, Ryo Nagao, Seiji Akimoto, Takehiro Suzuki, Naoshi Dohmae, Min Chen, Suleyman I. Allakhverdiev, Jian-Ren Shen, Fusamichi Akita, Naoyuki Miyazaki, Tatsuya Tomo, “Structural basis for the adaptation and function of chlorophyll f in photosystem I”, Nature Communications, 11, 238 (2020)
Y. Saga, M. Yamashita, M. Imanishi, Y. Kimura, Y. Masaoka, T. Hidaka, Y. Nagasawa, “Reconstitution of 3-Acetyl Chlorophyll a into Light-harvesting Complex 2 from the Purple Photosynthetic Bacterium Phaeospirillum molischianum”, ACS Omega, 5, 6817-6825 (2020)
Y. Saga, S. Nakagawa, “Structural Effects on Epimerization of Bacteriochlorophyll a and Chlorophyll a Revealed Using 3-Acetyl Chlorophyll a”, Journal of Porphyrins and Pthalocyanines, 24, 4, 499-504 (2020)
Y. Saga, M. Yamashita, S. Nakagawa, “In situ Conversion of Chlorophyll b Reconstituted into Photosynthetic Protein LH2”, Chemistry Letters, 48, 10, 1270-1273 (2019)
M. Imanishi, M. Takenouchi, S. Takaichi, S. Nakagawa, Y. Saga, S. Takenaka, M. T. Madigan, J. Overmann, Z.-Y. Wang-Otomo, Y. Kimura, “A Dual Role for Ca2+ in Expanding the Spectral Diversity and Stability of Light-Harvesting 1 Reaction Center Complexes of Purple Phototrophic Bacteria”, Biochemistry, 58, , 2844–2852 (2019)

公募B班
小島理沙、山元颯太、浅井智広、小澄大輔、大岡宏造, “Heliobacterium modesticaldum光合成反応中心への選択励起における励起エネルギー移動および電子移動反応”, 第30回光物性研究会 (2019)
Masaki Saigo, Kiyoshi Miyata, Sei’ichi Tanaka, Hajime Nakanotani, Chihaya Adachi, Ken Onda, “Suppression of Structural Change upon S1-T1 Conversion Assists Thermally Activated Delayed Fluorescence Process in Carbazole-Benzonitrile Derivatives”, J. Phys. Chem. Lett., 10, 2475 (2019)
Ken Onda, Kei Ohkubo, Yasuomi Yamazaki, Kazuhide Koike, Sei'ichi Tanaka, and Osamu Ishitani, “Direct Measurement of Intramolecular Electron Transfer in a Series of Artificial Photosynthesis Processes”, Ultrafast Phenomena XXI, 205, 9037 (2019)
Keiki Fukumoto, Ayşe Seyhan, Ken Onda, Shunri Oda, and Shinya Koshihara, “Comparison of picosecond electron dynamics in isolated and clustered Si quantum dots deposited on a semiconductor surface”, Appl. Phys. Lett., 115, 53105 (2019)
Yasuomi Yamazaki, Kei Ohkubo, Daiki Saito, Taiki Yatsu, Yusuke Tamaki, Sei’ichi Tanaka, Kazuhide Koike, Ken Onda, and Osamu Ishitani, “Kinetics and Mechanism of Intramolecular Electron Transfer in Ru(II)-Re(I) Supramolecular CO2-Reduction Photocatalysts: Effects of Bridging Ligands”, Inorg. Chem., 58, 11480 (2019)
Masaki Hada, Kiyoshi Miyata, Satoshi Ohmura, Yusuke Arashida, Kohei Ichiyanagi, Ikufumi Katayama, Takayuki Suzuki, Wang Chen, Shota Mizote, Takayoshi Sawa, Takayoshi Yokoya, Toshio Seki, Jiro Matsuo, Tomoharu Tokunaga, Chihiro Itoh, Kenji Tsuruta, Ryo Fukaya, Shunsuke Nozawa, Shinichi Adachi, Jun Takeda, Ken Onda, Shin-ya Koshihara, Yasuhiko Hayashi, Yuta Nishina, “Selective Reduction Mechanism of Graphene Oxide Driven by Photon Mode versus Thermal Mode”, ACS Nano, 13, 10103 (2019)
Kiyoshi Miyata, Ryota Nagaoka, Masaki Hada, Takanori Tanaka, Ryuji Mishima, Taihei Kuroda, Sota Sueta, Takumi Iida, Yoshifumi Yamashita, Takeshi Nishikawa, Kenji Tsuruta, Yasuhiko Hayashi, Ken Onda, Toshihiko Kiwa, Takashi Teranishi, “Liquid-like Dielectric Response is an Origin of Long Polaron Lifetime Exceeding Ten Microseconds in Lead Bromide Perovskites”, J. Chem. Phys., 152, 84704 (2020)
宮田潔志、西郷将生、恩田健, “熱活性化遅延蛍光材料の励起状態構造ダイナミクス”, 光化学, 50, 3, 189 (2019)
Yuya Inaba, Tomoki Yoneda, Yuichi Kitagawa, Kiyoshi Miyata, Yasuchika Hasegawa, Yasuhide Inokuma, “Splitting and reorientation of π-conjugation by an unprecedented photo-rearrangement reaction”, Chemical Communications, 56, 3, 348 (2020)
N. Murakami, K. Okuzono, “Determination of the internal quantum efficiency for photoelectrochemical reaction in a semiconductor photoelectrode by photoacoustic detection”, Chemical Communications (2020)
T. Shinoda, N. Murakami, “Photoacoustic Fourier Transform Near- and Mid-Infrared Spectroscopy for Measurement of Energy Levels of Electron Trapping Sites in Titanium(IV) Oxide Photocatalyst Powders”, The Journal of Physical Chemistry C, 123, 19, 12169-12175 (2019)
Kota Horiuchi, Chiasa Uragami, Taiki Inoue, Nao Yukihira, Daisuke Kosumi, Hideki Hashimoto, “Analysis on the excited state properties of cis-β-apo-8'-caortenal using femtosecond time-resolved absorption spectroscopy”, Carotenoid Science, 23, 24 (2019)
Daisuke Kosumi, Toshiyuki Kusumoto, and Hideki Hashimoto, “Anomalous Optical Properties of Artificial Short-Polyene Carotenoid”, Carotenoid Science, 23, 9 (2019)
Ryohei Akiyoshi, Yuma Hirota, Daisuke Kosumi, Mayu Tsutsumi, Masaaki Nakamura, Leonard F. Lindoy, and Shinya Hayami, “Ferroelectric metallomesogens composed of achiral spin crossover molecules”, Chemical Science, 10, 5843 (2019)
Yusuke Yoneda, Akari Goto, Nobutaka Takeda, Hiromi Harada, Masaharu Kondo, Hiroshi Miyasaka, Yutaka Nagasawa, Takehisa Dewa, “Ultrafast Photodynamics and Quantitative Evaluation of Biohybrid Photosynthetic Antenna and Reaction Center Complexes Generating Photocurrent”, J. Phys. Chem. C (2020)
Yoshitaka Saga, Madoka Yamashita, Michie Imanishi, Yukihiro Kimura, Yuto Masaoka, Tsubasa Hidaka, Yutaka Nagasawa, “Reconstitution of 3-Acetyl Chlorophyll a into Light-Harvesting Complex 2 from the Purple Photosynthetic Bacterium Phaeospirillum molischianum”, ACS Omega, 5, 12, 6817-6825 (2020)
Yusuke Yoneda, Yutaka Nagasawa, Yasufumi Umena, and Hiroshi Miyasaka, “β-Carotene Probes Energy Transfer Pathway in Photosystem II Core Complex”, J. Phys. Chem. Lett., 10, 13, 3710-3714 (2019)
M. Waki, S. Shirai, K. Yamanaka, Y. Maegawa, and S. Inagaki, “Heterogeneous water oxidation photocatalysis based on periodic mesoporous organosilica immobilizing a tris(2,20-bipyridine)ruthenium sensitizer”, RSC Advances, 10, 24, 13960-13967 (2020)
K. Yamanaka, Y. Maegawa, Y. Yamada, and S. Inagaki, “Excited-State Dynamics of 2,2′-Bipyridine Moieties Embedded in the Framework of Periodic Mesoporous Organosilica”, J. Phys. Chem. C, 123, 46, 28443-28449 (2019)
T. Suemoto, K. Yamanaka, and N. Sugimoto, “Observation of femtosecond infrared luminescence in gold”, Phys. Rev. B, 100, 0, 125405 (2019)
K. Yamanaka, “Excited-State Dynamics of Phenylene- and Biphenylene-Bridged Periodic Mesoporous Organosilica”, R&D Review of Toyota CRDL, 50, 2, 21-31 (2019)
T. Suemoto, N. Sugimoto, K. Nishikawa, K. Yamanaka, and S. Inagaki, “Observation of electron decay dynamics in Pt nano-structures by femtosecond infrared luminescence”, EPJ Web of Conference, 205, 4018 (2019)

公募C班
Wang Shuying、Teramura Kentaro、Hisatomi Takashi、Domen Kazunari、Asakura Hiroyuki、Hosokawa Saburo、Tanaka Tsunehiro, “Effective Driving of Ag-Loaded and Al-Doped SrTiO3 under Irradiation at λ > 300 nm for the Photocatalytic Conversion of CO2 by H2O”, ACS Applied Energy Materials, 3, 2, 1468-1475 (2020)
Justin S. J. Hargreaves, Young-Min Chung, Wha-Seung Ah, Takashi Hisatomi, Kazunari Domen, Mayfair C. Kung, Harold H. Kung, “Minimizing energy demand and environmental impact for sustainable NH3 and H2O2 production—A perspective on contributions from thermal, electro-, and photo-catalysis”, Applied Catalysis A: General, 594, 117419 (2020)
Naoya Tate and Takashi Yatsui, “Visible light-induced thymine dimerisation based on large localised field gradient by non-uniform optical near-field”, Scientific Reports, 9, 18383 (6 pages) (2019)
Takashi Yatsui, Yusuke Nakahira, Yuki Nakamura, Tatsuki Morimoto, Yuma Kato, Muneaki Yamamoto, Tomoko Yoshida, Kenji Iida, and Katsuyuki Nobusada, “Realization of red shift of absorption spectra using optical near-field effect”, Nanotechnology, 30, 34, 34LT02 (9 pages) (2019)
Takashi Tamaki, Keigo Minode, Yuichi Numai, Tatsuhiko Ohto, Ryo Yamada, Hiroshi Masaia, Hirokazu Tada, Jun Terao, “Mechanical Switching of Current-voltage Characteristics in Spiropyran Single-molecule Junctions”, Nanoscale, 12, 7527 (2020)
Kei Sawada, Takahisa Tanaka, Takamune Yokoyama, Ryosuke Yamachi, Yuki Oka, Yusuke Chiba, Hiroshi Masai, Jun Terao, Ken Uchida, “Co-Porphyrin Functionalized CVD Graphene Ammonia Sensor with High Selectivity to Disturbing Gases: Hydrogen and Humidity”, Jpn. J. App. Phys., 59, SGGG09 (2020)
Daiki Inamori, Hiroshi Masai, Takashi Tamaki, Jun Terao, “Macroscopic Change in Luminescent Color via Thermally Driven Sliding Motion in [3]Rotaxane”, Chem. Eur. J., 26, 3385 (2020)
Hiroshi Masai, Takuya Yokoyama, Hiromichi V. Miyagishi, Maning Liu, Yasuhiro Tachibana, Tetsuaki Fujihara, Yasushi Tsuj, Jun Terao, “Insulated Conjugated Bimetallopolymer with Sigmoidal Response by Dual Self-controlling System as a Biomimetic Material”, Nat. Commun., 11, 408 (2020)
Hiroshi Masai, Maning Liu, Yasuhiro Tachibana, Susumu Tsuda, Jun Terao, “Synthesis of Insulated Heteroaromatic Platinum–Acetylide Complexes with Color-Tunable Phosphorescence in Solution and Solid States”, J. Org. Chem., 85, 3082 (2020)
Shunichi Kaneko, Hiroshi Masai, Takuya Yokoyama, Manning Liu, Yasuhiro Tachibana, Tetsuaki Fujihara, Yasushi Tsuji, Jun Terao, “Complementary Color Tuning by Acid via Phosphorescence/Fluorescence Transition on Insulated Metallopolymer Film and Its Light-induced Acceleration”, Polymers, 12, 244 (2020)
Go M. Russell, Daiki Inamori, Hiroshi Masai, Takashi Tamaki, and Jun Terao, “Luminescent and Mechanical Enhancement of Phosphorescent Hydrogel through Cyclic Insulation of Platinum-acetylide Crosslinker”, Polym. Chem., 10, 5280 (2019)
Ce Zhou, Xingxing Li, Hiroshi Masai, ZIhao Liu, Yuanwei Lin, Takashi Tamaki, Jun Terao, Jinlong Yang, and Xuefeng Guo, “Revealing Charge-and Temperature-Dependent Movement Dynamics and Mechanism of Individual Molecular Machines”, Small Methods, 12, 1900464 (2019)
Yusuke Chiba, Yuki Oka, Hiroshi Masai, Wakana Matsuda, Tetsuaki Fujihara, Yasushi Tsuji, Jun Terao, “Two-Step Template Method for Synthesis of Axis-Length-Controlled Porphyrin-Containing Hollow Structures”, Chem. Commun., 55, 6755 (2019)
Chen Wang, Takuro Hosomi, Kazuki Nagashima, Tsunaki Takahashi, Guozhu Zhang, Masaki Kanai, Zeng Hao, Wataru Mizukami, Nobutaka Shioya, Takafumi Shimoaka, Takehiro Tamaoka, Hideto Yoshida, Seiji Takeda, Takao Yasui, Yoshinobu Baba, Yuriko Aoki, Jun Terao, Takeshi Hasegawa, Takeshi Yanagida, “Rational Method to Monitor Molecular Transformations on Metal Oxide Nanowire Surfaces”, Nano Lett., 19, 2443 (2019)
Sheng-Ying Chou, Hiroshi Masai, Susumu Tsuda, Jun Terao, “Synthetic Methodology for Structurally Defined and Insulated Molecular Wires Bearing Non‐centrosymmetric Conjugated Axle Components via Iterative Intramolecular Slippage”, Chem. Asian J., 14, 1667 (2019)
Hiromichi V. Miyagishi, Takashi Tamaki, Hiroshi Masai, Jun Terao, “Synthesis and Acid-Responsiveness of an Insulated π-Conjugated Polymer containing Spiropyrans in its Backbone”, Molecules, 24, 1301 (2019)
Go M. Russell, Hiroshi Masai, Jun Terao, “Platinum-Acetylide Crosslinkers for Facile Preparation of Phosphorescent Commodity Polymer Networks with Defect-Free Chromophores”, Mater. Lett., 247, 182 (2019)
Imran Khan, Reetam Kaushik, Ranjay K. Tiwari, Israel Mbomekalle, Pedro de Oliveira, Takashi Matono, Haruka Egawa, Ooyama, Masahiro Sadakane, Firasat Hussain, “Self-Assembled Tetrameric Lanthanide-Containing Germanotungstate [(Ln2GeW10O38)4(OH)4(H2O)2]26-: Syntheses, Crystal Structure, Photoluminescence and Electrochemical Properties”, ChemistrySelect, 4, 12668-12675 (2019)
Xian Zhang, Mihaela Cibian, Arnau Call, Kosei Yamauchi, and *Ken Sakai,, “Photochemical CO2 Reduction Driven by Water-Soluble Copper(I) Photosensitizer with the Catalysis Accelerated by Multi-Electron Chargeable Cobalt Porphyrin”, ACS Catalysis, 9, 12, 11263-11273 (2019)
Jia-Wei Wang, Kosei Yamauchi, Hai-Hua Huang, Jia-Kai Sun, Zhi-Mei Luo, Di-Chang Zhong, Tong-Bu Lu, and *Ken Sakai, “A Molecular Cobalt Hydrogen Evolution Catalyst Showing High Activity and Outstanding Tolerance to CO and O2”, Angewandte Chemie, 32, 58, 10923-10927 (2019)
Yuto Sakaguchi, Arnau Call, Mihaela Cibian, Kosei Yamauchi and *Ken Sakai, “An Earth-abundant System for Light-driven CO2 Reduction to CO Using a Pyridinophane Iron Catalyst”, Chemical Communication, 55, 8552-8555 (2019)
Arnau Call, Mihaela Cibian, Keiya Yamamoto, Takashi Nakazono, Kosei Yamauchi, and *Ken Sakai, “Highly Efficient and Selective Photocatalytic CO2 Reduction to CO in Water by a Cobalt Porphyrin Molecular Catalyst”, ACS Catalysis, 6, 9, 4867-4874 (2019)
Alexander Rene Parent, Takashi Nakazono, Yuta Tsubonouchi, Natsuki Taira and *Ken Sakai, “Mechanisms of Water Oxidation using Ruthenium, Cobalt, Copper, and Iron Molecular Catalysts”, Advances in Inorganic Chemistry, , 74, 197-240 (2019)
Tomoya Ishibashi, Masanobu Higashi, Shigeru Ikeda, Yutaka Amao, “Photoelectrochemical CO2 Reduction to Formate with the Sacrificial Reagent Free System of Semiconductor Photocatalysts and Formate Dehydrogenase”, ChemCatChem, 11, 6227–6235 (2019)
Shusaku Ikeyama, Shota Hizume, Tatsuya Takahashi, Shin Ogasawara, Yutaka Amao and Hitoshi Tamiaki, “Visible-light driven hydrogen production using chlorophyll derivatives conjugated a viologen moiety in the presence of platinum nanoparticles”, Photochemical & Photobiological Sciences, 18, 2673–2681 (2019)
Yusuke Minami ,Yumiko Muroga ,Tomoko Yoshida , Yutaka Amao, “Selective Hydrogen Production from Formate Using Nanoparticle with Homogeneously Polymer-dispersed Platinum Clusters”, Chemistry Letters, 48, 8, 775-778 (2019)
Takayuki Katagiri, Yutaka Amao, “Double-Electron Reduced Diphenylviologen as a Coenzyme for Biocatalytic Building Carbon–Carbon Bonds from CO2 as a Carbon Feedstock”, ACS Sustainable Chemistry & Engineering, 7, 10, 9080-9085 (2019)
Yosuke Kageshima, Takumi Fujita, Fumiaki Takagi, Tsutomu Minegishi, Katsuya Teshima, Kazunari Domen, Yutaka Amao, Hiromasa Nishikiori, “Electrochemical Evaluation for Multiple Functions of Pt loaded TiO2 Nanoparticles Deposited on a Photocathode”, ChemElectroChem, 6, 4859–4866 (2019)
Hitoshi Ishida, Charles Machan, Marc Robert and Nobuharu Iwasawa, “Editorial: Molecular Catalysts for CO2 Fixation/Reduction”, Frontiers in Chemistry, 8, 59 (2020)
Mari Toyama, Takako Takizawa, Itaru Morita, Noriharu Nagao, Yusuke Kuramochi, Hitoshi Ishida, “New Heteroleptic Bis(Bidentate) Ruthenium(II) Complexes with Two Different Monodentate Ligands, trans(Cl,Nbpy)- and trans(Cl,NHdpa)- [Ru(bpy)Cl(Hdpa)(dmso-S)]+: Syntheses, Structures, and Characterization”, Chem. Eur. J., 25, 72, 16582-16590 (2019)
W. Kurashige, Y. Mori, S. Ozaki, M. Kawachi, S. Hossain, T. Kawawaki, C. J. Shearer, A. Iwase, G. F. Metha, S. Yamazoe, A. Kudo, *Y. Negishi, “Activation of Water-Splitting Photocatalysts by Loading with Ultrafine Rh–Cr Mixed-Oxide Cocatalyst Nanoparticles”, Angewandte Chemie International Edition, 59, 18, 7076–7082 (2020)
T. Kawawaki, *Y. Negishi, “Gold Nanoclusters as Electrocatalysts for Energy Conversion”, Nanomaterials, 10, 2, 238 (2020)
T. Kawawaki, *Y. Negishi, *H. Kawasaki, “Photo/electrocatalysis and photosensitization using metal nanoclusters for green energy and medical applications”, Nanoscale Advances, 2, 1, 17–36 (2020)
W. Kurashige, R. Hayashi, K. Wakamatsu, Y. Kataoka, S. Hossain, A. Iwase, A. Kudo, *S. Yamazoe, *Y. Negishi, “Atomic-Level Understanding of the Effect of Heteroatom Doping of the Cocatalyst on Water-Splitting Activity in AuPd or AuPt Alloy Cluster-Loaded BaLa4Ti4O15”, ACS Applied Energy Materials, 2, 6, 4175–4187 (2019)
I. Abdellaoui, M. M. Islam, M. Remeika, H. Yui, T. Harada, T. Maeda, C. Budich, T. Wada, S. Ikeda, and *T. Sakurai, “Photocarrier recombination dynamics in BiVO4 for visible light-driven water oxidation”, J. Phys. Chem. C, 124, 7, 3962-3972 (2020)
*Y. Amao, T. Ishibashi, M. Higashi, and S. Ikeda, “Photoelectrochemical CO2 reduction to formate with the sacrificial reagent free system of semiconductor photocatalysts and formate dehydrogenase”, ChemCatChem, 11, 1-10 (2019)
*S. Ikeda, S. Fujikawa, T. Harada, T. H. Nguyen, S. Nakanishi, T. Takayama, A. Iwase, A. Kudo, “Photocathode characteristics of a spray-deposited Cu2ZnGeS4 thin film for CO2 reduction in a CO2-saturated aqueous solution”, 2, 9, 6911-6918 (2019)
K. Wang, D. Huang, L. Yu, K. Feng, L. Li, T. Harada, S. Ikeda, and *F. Jiang, “Promising GeSe nanosheet based thin film photocathode for efficient and stable overall solar water splitting”, ACS Catal., 9(4),, 9, 4, 3090-3097 (2019)
S. Inoue, Y.-N. Yan, K. Yamanishi, Y. Kataoka, T. Kawamoto, “Photocatalytic and electrocatalytic hydrogen production using nickel complexes supported by hemilabile and non-innocent ligands”, Chemical Communications, 56, 2829-2832 (2020)
Y. Kataoka, N. Yano, Y. Kohara, T. Tsuji, S. Inoue, T. Kawamoto, “Experimental and Theoretical Study of Photochemical Hydrogen Evolution Catalyzed by Paddlewheel-type Dirhodium Complexes with Electron Withdrawing Carboxylate Ligands”, ChemCatChem, 11, 24, 6218-6226 (2019)
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