光合成分子機構の学理解明と時空間制御による革新的光ー物質変換系の創製

研究成果

原著論文　2020年度

論文2017年度 / 論文2018年度 / 論文2019年度 / 論文2020年度 / 論文2021年度

計画班A01	計画班A02	計画班A03	計画班B01	計画班B02
計画班C01	計画班C02	公募A班	公募B班	公募C班

計画班A01

Nagao R., Yokono M., Ueno Y., Suzuki T., Kumazawa, M. Kato K.-H., Tsuboshita N., Dohmae N., Ifuku K., Shen J.-R., Akimoto S., “Enhancement of excitation-energy quenching in fucoxanthin chlorophyll a/c-binding proteins isolated from a diatom Phaeodactylum tricornutum upon excess-light illumination”, Biochim. Biophys. Acta Bioenerg., 1862, 2, 148350 (2021)

Nagao R., Yokono M., Ueno Y., Suzuki T., Kato K., Kato K.-H., Tsuboshita N., Jiang T.-Y., Dohmae N., Shen J.-R., Ehira S., Akimoto S., “Molecular organizations and function of iron-stress-induced-A protein family in Anabaena sp. PCC 7120”, Biochim. Biophys. Acta Bioenerg., 1862, 1, 148327 (2021)

Nagao R., Yokono M., Ueno Y., Kato K.-H., Tsuboshita N., Shen J.-R., Akimoto S., “Basic pH-induced modification of excitation-energy dynamics in fucoxanthin chlorophyll a/c-binding proteins isolated from a pinguiophyte, Glossomastix chrysoplasta”, Biochim. Biophys. Acta Bioenerg., 1862, 1, 148306 (2021)

Taguchi S., Shen L., Han G., Umena Y., Shen J.-R., Noguchi T., Mino H., “Formation of the high-spin S₂ state related to the extrinsic proteins in the oxygen evolving complex of photosystem II”, J. Phys. Chem. Lett., 11, 8908-8913 (2020)

Nagao R., Yokono M., Ueno Y., Shen J.-R., Akimoto S., “Reply to "Comment on 'acidic ph-induced modification of energy transfer in diatom fucoxanthin chlorophyll a/c-binding proteins””, J. Phys. Chem. B., 124, 46, 10588-10589 (2020)

Xu C., Pi X., Huang Y., Han G., Chen X., Qin X., Huang G., Zhao S., Yang Y., Kuang T., Wang W., Sui S.-F., Shen J.-R., “Structural basis for energy transfer in a huge diatom PSI-FCPI supercomplex”, Nat. Commun., 11, 5081 (2020)

Chen J.-H., Wu H., Xu C., Liu X.-C., Huang Z., Chang S., Wang W., Han G., Kuang T., Shen J.-R., Zhang X., “Architecture of the photosynthetic complex from a green sulfur bacterium”, Science, 370, 6519, eabb6350 (2020)

Chang L., Tian L., Ma F., Mao Z., Liu X., Han G., Wang W., Yang Y., Kuang T., Pan J., Shen J.-R., “Regulation of photosystem I-light-harvesting complex I from a red alga Cyanidioschyzon merolae in response to light intensities”, Photosynth. Res., 146, 287–297 (2020)

Nagao R., Kato K., Ifuku K., Suzuki T., Kumazawa M., Uchiyama I., Kashino Y., Dohmae N., Akimoto S., Shen J.-R., Miyazaki N., Akita F., “Structural basis for assembly and function of a diatom photosystem I-light harvesting supercomplex”, Nat. Commun., 11, 1, 2481 (2020)

Xiao Y., Zhu Q., Yang Y., Wang W., Kuang T., Shen J.-R., Han G., “Role of PsbV-Tyr137 in photosystem II studied by site-directed mutagenesis in the thermophilic cyanobacterium Thermosynechococcus vulcanus”, Photosynth. Res., 146, 41–54 (2020)

Nagao R., Yokono M., Ueno Y., Shen J.-R., Akimoto S., “Acidic pH-induced modification of energy transfer in diatom fucoxanthin chlorophyll a/c-binding proteins”, J. Phys. Chem. Part B, 124, 4919-4923 (2020)

Akita F., Nagao R., Kato K., Nakajima Y., Yokono M., Ueno Y., Suzuki T., Dohmae N., Shen J.-R., Akimoto S., Miyazaki N., “Structure of a cyanobacterial photosystem I surrounded by octadecameric IsiA antenna proteins”, Comm. Biol., 3, 1, 232 (2020)

Ouyang M., Li X., Zhang J., Feng P., Pu H., Kong L., Bai Z., Rong L., Xu, X. Chi W., Wang Q., Chen F., Lu C., Shen J., Zhang L., “Liquid-liquid phase transition drives intra-chloroplast cargo sorting”, Cell, 180, 1144-1159 (2020)

Akhtar P., Nowakowski P. J., Wang W., Do T. N., Zhao S., Siligardi G., Garab G., Shen J.-R., Tan H.-S., Lambrev P. H., “Spectral tuning of light-harvesting complex II in the siphonous alga Bryopsis corticulans and its effect on energy transfer dynamics”, Biochim. Biophys. Acta Bioenerg., 1861, 7, 148191 (2020)

Nagao R., Ueno Y., Akimoto S., Shen J.-R., “Effects of CO₂ and temperature on photosynthetic performance in the diatom Chaetoceros gracilis”, Photosynth. Res., 146, 189–195 (2020)

Tanabe M., Ueno Y., Yokono M., Shen J.-R., Nagao R., Akimoto S., “Changes in excitation relaxation of diatoms in response to fluctuating light, probed by fluorescence spectroscopies”, Photosynth. Res., 146, 143–150 (2020)

Nagao R., Yokono M., Ueno Y., Jiang T.-Y., Shen J.-R., Akimoto S., “pH-induced regulation of excitation energy transfer in cyanobacterial photosystem I tetramer”, J. Phys. Chem. Part B, 124, 10, 1949-1954 (2020)

Nagao R., Yokono M., Ueno Y., Shen J.-R., Akimoto S., “Excitation energy transfer and quenching in diatom PSI-FCPI upon P700 cation formation”, J. Phys. Chem. Part B, 124, 8, 1481-1486 (2020)

Zhu Q., Yang Y., Xiao Y., Wang W., Kuang T., Shen J.-R., Han G., “Function of PsbO-Asp158 in Photosystem II: Effects of mutation of this residue on the binding of PsbO and function of PSII in Thermosynechococcus vulcanus”, Photosynth. Res., 146, 29–40 (2020)

Wang W., Zhao S., Pi X., Kuang T., Sui S.-F., Shen J.-R., “Structural features of the diatom photosystem II–light-harvesting antenna complex”, FEBS J., 287, 2191–2200 (2020)

Oka K., Ueno Y., Yokono M., Shen J.-R., Nagao R., Akimoto S., “Adaptation of light-harvesting and energy-transfer processes of a diatom Phaeodactylum tricornutum to different light qualities”, Photosynth. Res., 146, 227–234 (2020)

Akimoto S., Ueno Y., Yokono M., Shen J.-R., Nagao R., “Adaptation of light-harvesting and energy‑transfer processes　of a diatom Chaetoceros gracilis to different light qualities”, Photosynth. Res., 146, 87–93 (2020)

Kato Y., Haniu S., Nakajima Y., Akita F., Shen J.-R., Noguchi T., “FTIR microspectroscopic analysis of the water oxidation reaction in a single photosystem II microcrystal”, J. Phys. Chem. B., 124, 1, 121-127 (2020)

Najafpour M. M., Zaharieva I., Zand Z., Hosseini S. M., Kouzmanova M., Hołynska M., Tranca I., Larkum A. W., Shen J.-R., Allakhverdiev S. I., “Water-oxidizing complex in Photosystem II: Its structure and relation to manganese-oxide based catalysts”, Coord. Chem. Rev., 409, 213183 (2020)

Suga M., Shen J.-R., “Structural variations of photosystem I-antenna supercomplex in response to adaptations to different light environments”, Curr. Opin. Struct. Biol., 63, 10–17 (2020)

T. Shimamoto, T. Nakakubo, T. Noji, S. Koeda, K. Kawakami, N. Kamiya, T. Mizuno, “Design of PG-surfactants bearing polyacrylamide polymer chain to solubilize membrane proteins in a surfactant-free buffer”, Int. J, Mol. Sci., 22, 1542 (2021)

神谷信夫, “生命科学の飛躍のために一層深まるタンパク質結晶学の役割－ X線結晶構造解析と構造生物化学”, 日本結晶学会誌, 62, 99-105 (2020)

K. Miyagawa, T. Kawakami, Y. Suzuki, H. Isobe, M. Shoji, S. Yamanaka, M. Okumura, T. Nakajima and K. Yamaguchi, “Relative stability among intermediate structures in S2 state of CaMn₄O₅ cluster in PSII by using hybrid-DFT and DLPNO-CC methods and evaluation of magnetic interactions between Mn ions”, J. Photochem. Photobiol. A, 405, 112923 (16 pages) (2021)

K. Miyagawa, H. Isobe, M. Shoji, T. Kawakami, S. Yamanaka and K. Yamaguchi, “A three states model for hydrogen abstraction reactions with the cytochrome P450 compound I is revisited. Isolobal and isospin analogy among Fe(IV)=O, O = O and O”, J. Photochem. Photobiol. A, 405, 112902 (14 pages) (2021)

K. Yamaguchi, H. Isobe, M. Shoji, K. Miyagawa, S. Yamanaka, T. Kawakami and T. Nakajima, “Development of broken-symmetry (BS) methods in chemical reactions. A theoretical view of water oxidation in photosystem II and related systems”, J. Photochem. Photobiol. A, 402, 112791 (22 pages) (2020)

K. Miyagawa, S. Yamanaka, H. Isobe, M. Shoji, T. Kawakami, M. Taniguchi, M. Okumura and K. Yamaguchi, “Electronic and spin structures of CaMn₄Ox clusters in the S0 state of the oxygen evolving complex of photosystem II. Domain-based local pair natural orbital (DLPNO) coupled-cluster (CC) calculations using optimized geometries and natural orbitals (UNO) by”, Phys. Chem. Chem. Phys., 22, 27191-27205 (2020)

K. Miyagawa, M. Shoji, H. Isobe, S. Yamanaka, T. Kawakami, M. Okumura and K. Yamaguchi, “UNO(ULO) active space for multireference calculations on classical and quantum computers. Revisit to the iron-sulfur complexes”, Chem. Phys. Lett., 746, 137252 (9 pages) (2020)

K. Miyagawa, M. Shoji, H. Isobe, S, Yamanaka, T. Kawakami, M. Okumura and K. Yamaguchi, “Theory of chemical bonds in metalloenzymes XXIV electronic and spin structures of FeMoco and Fe-S clusters by classical and quantum computing”, Mol. Phys., 118, e1760388 (28 pages) (2020)

山口兆、庄司光男、磯部寛、川上貴資、宮川晃一、中嶋隆人, “化学反応における対称性の破れの理論（10）：光合成水分解CaMn₄O₆クラスターのXFEL光を用いたSFX法によるS3中間体構造再訪”, 豊田研究報告, 73, 113-130 (2020)

計画班A02

M. Kimura, Y. Kato, and T. Noguchi, “Protonation state of a key histidine ligand in the iron-quinone complex of photosystem II as revealed by light-induced ATR-FTIR spectroscopy,”, Biochemistry,, 59, 45, 4336–4343 (2020)

M. Yamamoto, S. Nakamura, and T. Noguchi, “Protonation structure of the photosynthetic water oxidizing complex in the S0 state as revealed by normal mode analysis using quantum mechanics/molecular mechanics calculations,”, Phys. Chem. Chem. Phys.,, 22, 42, 24213–24225 (2020)

S. Taguchi, L. Shen, G. Han, Y. Umena, J.-R. Shen, T. Noguchi, and H. Mino, “Formation of the high-spin S₂ state related to the extrinsic proteins in the oxygen evolving complex of photosystem II,”, J. Phys. Chem. Lett.,, 11, 20, 8908–8913 (2020)

T. Tokano, Y. Kato, S. Sugiyama, T. Uchihashi, and T. Noguchi, “Structural dynamics of a protein domain relevant to the water-oxidizing complex in photosystem II as visualized by high-speed atomic force microscopy,”, J. Phys. Chem. B,, 124, 28, 5847–5857 (2020)

S. Taguchi, T. Noguchi, and H. Mino, “Molecular Structure of the S₂ state with a g = 5 signal in the oxygen evolving complex of photosystem II,”, J. Phys. Chem. B,, 124, 27, 5531–5537 (2020)

K. Kawahara, N. Inoue-Kashino, K. Namie, Y. Kato, T. Tomo, Y. Shibata, Y. Kashino, and T. Noguchi, “A gold nanoparticle conjugate with photosystem I and photosystem II for development of a biohybrid water-splitting photocatalyst”, Biomed. Spectrosc. Imaging,, 9, 0, 73-81 (2020)

Sugiura, M., Taniguchi, T., Tango, N., Nakamura, M., Sellés, J., and Boussac, A., “Probing the role of Arginine 323 of the D1 protein in Photosystem II function”, Physiol. Plant., 171, 183-199 (2021)

杉浦美羽, “明らかにされつつある光合成によるエネルギー変換のしくみと応用への期待”, 電気評論, 0, 18-25 (2021)

Boussac, A., Sellés, J., and Sugiura, M., “What can we still learn from the electrochromic band-shifts in Photosystem II?”, Biochim. Biophys. Acta (Bioenergetics), 1861, 148176 (2020)

計画班A03

M. Hirose, M. Teramura, J. Harada, H. Tamiaki, “BciC-catalyzed C13²-demethoxycarbonylation of metal pheophorbide a alkyl esters”, ChemBioChem, 21, 10, 1473-1480 (2020)

H. Watanabe, S. Nakamura, H. Tamiaki, “Sterically controlled and pH-dependent self-aggregation of synthetic zinc 3-(alkylamino)methylated chlorophyll-a derivatives in aqueous micellar solution”, J. Porphyrins Phthalocyanines, 24, 0, 685-692 (2020)

T. Nakano, H. Tamiaki, “Synthesis and self-aggregation of chlorophyll-a derivatives inserting ethylene and phenylene groups between hydroxymethyl group and chlorin π-skeleton”, ChemPhotoChem, 4, 5, 338-346 (2020)

Y. Li, Y. Sun, X. Meng, Y. Dall'Agnese, G. Chen, C. Dall'Agnese, S. Sasaki, H. Tamiaki, X.-F. Wang, “Chlorosome-like molecular aggregation of chlorophyll derivative of Ti₃C₂T_x nanosheets for efficient noble metal-free photocatalytic hydrogen evolution”, Adv. Mater. Interfaces, 7, 8, 1902080 (2020)

Y. Shinozaki, C. Uragami, H. Hashimoto, H. Tamiaki, “A synthetic dimer appending fullerene: effect of chlorophyll pairing on (photo)redox properties”, Chem. Eur. J., 26, 41, 8897-8906 (2020)

T. Nakano, H. Tamiaki, “Self-aggregation abilities of synthetic bacteriochlorophyll-d analogs bearing a propargyl- and benzyl-type alcohol”, J. Photochem. Photobiol. A: Chem., 397, 112556 (2020)

A. Katayama, H. Tamiaki, “Stereoselective self-aggregation of zinc bacteriochlorophyll-d analogs possessing an O-substituted oxime moiety at the 13-position”, J. Photochem. Photobiol. A: Chem., 400, 112554 (2020)

S. Duan, Q. Zhou, A. Li, X.-F. Wang, S. Sasaki, H. Tamiaki, “Semisynthetic chlorophyll derivatives toward solar energy applications”, Solar RRL, 4, 6, 2000162 (2020)

C. Zhang, W. Zhao, S. Sasaki, H. Tamiaki, X.-F. Wang, “A chlorophyll derivatives-based bio-solar energy conversion and storage device”, Electrochim. Acta, 347, 136283 (2020)

M. Kishi, Y. Nakamura, H. Tamiaki, “Effect of additional hydroxy group on self-aggregation of synthetic zinc bacteriochlorophyll-c analogs”, J. Photochem. Photobiol. A: Chem., 400, 112592 (2020)

B. Wang, L. Yang, C. Dall'Agnese, A. K. Jena, S. Sasaki, T. Miyasaka, H. Tamiaki, X.-F. Wang, “Photoactive Zn-chlorophyll hole transporter-sensitized lead-free Cs₂AgBiBr₆ perovskite solar cells”, Solar RRL, 4, 7, 2000166 (2020)

T. Takeda, A. Katayama, Y. Kinoshita, H. Tamiaki, “Synthesis of zinc oxime-functionalized chlorophyll-a derivatives and their (13¹E/Z)-dependent self-aggregation”, Tetrahedron, 76, 0, 131300 (2020)

T. Miyatake, K. Okada, Y. Yamamoto, R. Hirai, R. Inoue, T. Imai, H. Tamiaki, “Amphiphilic zinc chlorin as an effective gelator in methanol–water mixtures”, J. Photochem. Photobiol. A: Chem., 400, 112683 (2020)

S. Matsubara, H. Tamiaki, “Growth model of chlorosome antenna by the environment-dependent stepwise assembly of a zinc chlorophyll derivative”, Photosynth. Res., 145, 2, 129-134 (2020)

Y. Fujiwara, T. Takeda, S. Ogasawara, H. Tamiaki, “Facile 13²-methylation of chlorophyll-a derivative and (13²R/S)-stereoselective self-aggregation of zinc bacteriochlorophyll-d anal”, Tetrahedron Lett., 61, 31, 152167 (2020)

M. Hirose, M. Teramura, J. Harada, S. Ogasawara, H. Tamiaki, “In vitro C13²-dealkoxycarbonylations of zinc chlorophyll a derivatives including C13²-substitutes by a BciC enzyme”, Bioorg. Chem., 102, 104111 (2020)

S. Ogasawara, K. Nakano, H. Tamiaki, “Synthesis of fluorinated chlorophyll-a and their bio/physico-chemical properties”, Eur. J. Org. Chem., 34, 5537-5543 (2020)

S. Matsubara, H. Tamiaki, “Supramolecular chlorophyll aggregates inspired from specific light-harvesting antenna "chlorosome": Static nanostructure, dynamic construction process, and versatile application”, J. Photochem. Photobiol. C: Photochem. Rev., 45, 100385 (2020)

D. Funakoshi, Y. Nomura, S. Shoji, H. Tamiaki, “Zinc 7,8-dihydroxylated chlorophyll-a derivative as a synthetic model of natural bacteriochlorophyll-a”, Chem. Lett., 49, 11, 1403-1405 (2020)

S. Naka, T. Shoji, S. Fujii, K. Ueno, Y. Wakisaka, K. Murakoshi, T. Mizoguchi, H. Tamiaki, Y. Tsuboi, “Thermo-plasmonic trapping of living cyanobacteria on a gold nanopyramidal dimer array: Implications for plasmonic biochips”, ACS Appl. Nano Mater., 3, 10, 10067-10072 (2020)

S. Ogasawara, K. Nakano, H. Tamiaki, “Site-selective C20-fluorination of chlorophyll-a derivatives using N-fluorobenzenesulfonimide and their optical properties”, Tetrahedron, 76, 52, 131722 (2020)

Y. Saga, Y. Otsuka, D. Funakoshi, Y. Masaoka, Y. Kihara, T. Hidaka, H. Hatano, H. Asakawa, Y. Nagasawa, H. Tamiaki, “In situ formation of photoactive B-ring reduced chlorophyll isomer in photosynthetic protein LH2”, Sci. Rep., 10, 19383 (2020)

S. Sasaki, Y. Hashimoto, Y. Kinoshita, H. Tamiaki, S. Duan, X-F. Wang, M. Yamashita, Y. Saga, H. Yamamoto, T. Ikeuchi, N. Shishioh, “Synthesis of C3/C13-substituted semi-synthetic bacteriochlorophyll-a derivatives and their properties as functional dyes”, ChemPhotoChem, 4, 12, 5399-5407 (2020)

M. Hirose, J. Harada, H. Tamiaki, “In vitro hydrolysis of zinc chlorophyllide a homologues by a BciC enzyme”, Biochemistry, 59, 49, 4622-4626 (2020)

Y. Kawamoto, Y. Nagano, Y. Kitagawa, H. Tamiaki, “Synthesis of N-methylated unsymmetric porphyrinoids with restricted N-centered chirality from natural chlorophyll-a”, Org. Biomol. Chem., 18, 48, 9800-9804 (2020)

S. Duan, L. Wang, W. Zhao, J. Du, L. Pan, N. Tamai, S. Sasaki, H, Tamiaki, X.-F. Wang, “Charge-transfer mechanism in chlorophyll derivative-based biosolar cells with hole-transporting P3HT revealed by sub-picosecond transient absorption spectroscopy”, J. Phys. Chem. C, 124, 51, 27900-27906 (2020)

J. Harada, T. Mizoguchi, Y. Kinoshita, K. Yamamoto, H. Tamiaki, “Over-expression of C8²-methyltransferase BchQ in the green sulfur bacterium Chlorobaculum limnaeum mutant strains of synthesis of C8-hyper-alkylated chlorosomal pigments”, J. Photochem. Photobiol. A: Chem., 404, 112882 (2021)

D. Funakoshi, S. Matsubara, H. Tamiaki, “Self-aggregation of zinc bacteriochlorophyll-d analog bearing B-ring reduced chlorin and 17-acrylate residue”, Tetrahedron, 81, 131853 (2021)

Y. Li, Y. Sun, Y. Dall'Agnese, C. Dall'Agnese, X. Meng, S. Sasaki, H, Tamiaki, X.-F. Wang, “Chlorophyll-based organic heterojunction on Ti₃C₂Tx MXenes nanosheets for efficient hydrogen production”, Chem. Eur. J., 27, 16, 5277-5282 (2021)

B. Wang, N. Li, L. Yang, C. Dall'Agnese, A. K. Jena, S. Sasaki, T. Miyasaka, H. Tamiaki, X.-F. Wang, “Chlorophyll derivative-sensitized TiO₂ electron transport layer for record efficiency of Cs₂AgBiBr₆ double perovskite solar cells”, J. Am. Chem. Soc., 143, 5, 2207-2211 (2021)

D. Funakoshi, H. Tamiaki, “Synthesis of 18-formylated B-ring reduced chlorophyll derivative as a heme A analog and effect of the 18-substituents on optical properties”, Tetrahedron Lett., 68, 152921 (2021)

M. Hirose, J. Harada, H. Tamiaki, “Detection of 13²-carboxy-chlorin produced by the in vitro BciC enzymatic hydrolysis of zinc chlorophyllide”, Bioorg. Med. Chem. Lett., 40, 127931 (2021)

計画班B01

Uragami Chiasa、Sato Hiroki、Yukihira Nao、Fujiwara Masazumi、Kosumi Daisuke、Gardiner Alastair T.、Cogdell Richard J.、* Hashimoto Hideki, “Photoprotective mechanisms in the core LH1 antenna pigment-protein complex from the purple photosynthetic bacterium, Rhodospirillum rubrum”, Journal of Photochemistry and Photobiology A: Chemistry, 400, 112628 (2020)

Shinozaki Yoshinao、Uragami Chiasa、Hashimoto Hideki、*Tamiaki Hitoshi, “A Synthetic Chlorophyll Dimer Appending Fullerene: Effect of Chlorophyll Pairing on (Photo)redox Properties”, Chemistry ー A European Journal, 26, 8897-8906 (2020)

Sera Yoshihiko、Seto Shota、Isobe Kiyoshi、*Hashimoto Hideki, “Development of highly active hydrogen evolution reaction (HER) catalysts composed of reduced graphene oxide and amorphous molybdenum sulfides derived from (NH₄)₂MoO_mS_4-m (m = 0, 1, and 2)”, Journal of Photochemistry and Photobiology A: Chemistry, 401, 112793 (2020)

*Sakaguchi Kazuhiko、Nishioka Yuto、Kinashi Naoto、Yukihira Nao、Shinada Tetsuro、Nishimura Takahiro、Hashimoto Hideki、Katsumura Shigeo, “Synthesis of Allene-Containing Apocarotenoids by Cross-Coupling Strategy”, Synthesis, 52, 3007-3017 (2020)

*Saga Yoshitaka、Miyagi Kanji、Sato Hiroki、Uragami Chiasa、Hashimoto Hideki, “Effects of palladium ions on light-harvesting complex 2 lacking B800 bacteriochlorophyll a”, Journal of Photochemistry and Photobiology A: Chemistry, 398, 112593 (2020)

Miyasato Ryo、Fujiwara Masazumi、Uragami Chiasa、Sato Haruyuki、Yano Toshihiro、*Hashimoto Hideki, “Operando time-resolved diffuse reflection spectroscopy: The origins of photocatalytic wateroxidation activity of bismuth vanadate”, Journal of Photochemistry and Photobiology A: Chemistry, 395, 112493 (2020)

Kojima Risa、Yamamoto Hayata、Azai Chihiro、Uragami Chiasa、Hashimoto Hideki、Kosumi Daisuke、 *Oh-oka Hirozo, “Energy transfer and primary charge separation upon selective femtosecond excitation at 810 nm in the reaction center complex from Heliobacterium modesticaldum”, Journal of Photochemistry and Photobiology A: Chemistry, 401, 112758 (2020)

Mitarai Mayu、Yoshida Marina、Yukihira Nao、Uragami Chiasa、Horiuchi Kota、Hashimoto Hiroki、 Gardiner Alastair T.、Cogdell Richard J.、*Hashimoto Hideki, “Reconstitution of carotenoids into the reaction center from the purple photosynthetic bacterium Rhodobacter sphaeroides using the chromatophores of the carotenoidless strain R26.1”, Carotenoid Science, 24, 36-40 (2020)

*Akihito Ishizaki, *G.R.Fleming, “Insights into photosynthetic energy transfer gained from free-energy structure: coherent transport, incoherent hopping, and vibrational assistance revisited”, Journal of Physical Chemistry B, 125, 3286-3295 (2021)

Akihito Ishizaki, “Probing excited-state dynamics with quantum entangled photons: correspondence to coherent multidimensional spectroscopy”, Journal of Chemical Physics, 153, 51002.1-51002.7 (2020)

*Nguyen Thanh Phuc, Pham Quang Trung, Akihito Ishizaki, “Controlling the nonadiabatic electron-transfer reaction rate through molecular-vibration polaritons in the ultrastrong coupling regime”, Scientific Reports, 10, 7318.1-7318.11 (2020)

Yuta Fujihashi, Ryosuke Shimizu, *Akihito Ishizaki, “Generation of pseudo-sunlight via quantum entangled photons and the interaction with molecules”, Physical Review Research, 2, 23256.1-23256.7 (2020)

計画班B02

H. Kim, J. G. Kim, T. W. Kim, S. J. Lee, S. Nozawa, S. I. Adachi, K. Yoon, J. Kim, H. Ihee, “Ultrafast Structural Dynamics of in-Cage Isomerization of Diiodomethane in Solution”, Chemical Science, 12, 2114-2120 (2021)

K. Watanabe, K. Iwashina, A. Iwase, S. Nozawa, S. I. Adachi, A. Kudo, “New Visible-Light-Driven H₂- and O₂-Evolving Photocatalysts Developed by Ag(I) and Cu(I) Ion Exchange of Various Layered and Tunneling Metal Oxides Using Molten Salts Treatments”, Chemistry of Materials, 32, 10524-10537 (2020)

Y. Uemura, T. Yokoyama, T. Katayama, S. Nozawa, K. Asakura, “Tracking the Local Structure Change During the Photoabsorption Processes of Photocatalysts by the Ultrafast Pump-Probe Xafs Method”, Applied Sciences, 10, 1-15 (2020)

S. Takagi, A. Kyono, S. Nozawa, N. Kawai, K. Inukai, R. Fukaya, N. Funamori, S. I. Adachi, K. Ichiyanagi, “In Situ Observation of the Phase Transition Behavior of Shocked Baddeleyite”, Geophysical Research Letters, 47, e2020GL089592 (2020)

K. Sato, K. I. Yamanaka, S. Nozawa, H. Fukuzawa, T. Katayama, T. Morikawa, T. Nonaka, K. Dohmae, K. Ueda, M. Yabashi, R. Asahi, “Charge Trapping Process in Photoexcited Nitrogen-Doped Titanium Oxides”, Inorg Chem, 59, 10439-10449 (2020)

K. Mio, M. Ishihara, S. Fujimura, D. Sasaki, S. Nozawa, K. Ichiyanagi, R. Fukaya, S. I. Adachi, M. Kuramochi, H. Sekiguchi, T. Kubo, Y. C. Sasaki, “X-Ray-Based Living-Cell Motion Analysis of Individual Serotonin Receptors”, Biochem Biophys Res Commun, 529, 306-313 (2020)

J. G. Kim, S. Nozawa, H. Kim, E. H. Choi, T. Sato, T. W. Kim, K. H. Kim, H. Ki, J. Kim, M. Choi, Y. Lee, J. Heo, K. Y. Oang, K. Ichiyanagi, R. Fukaya, J. H. Lee, J. Park, I. Eom, S. H. Chun, S. Kim, M. Kim, T. Katayama, T. Togashi, S. Owada, M. Yabashi, S, “Mapping the Emergence of Molecular Vibrations Mediating Bond Formation”, Nature, 582, 520-524 (2020)

T. Kanazawa, R. Yamaguchi, T. Uchiyama, D. Lu, S. Nozawa, Y. Uchimoto, K. Maeda, “Structure-Activity Relationship in a Cobalt Aluminate Nanoparticle Cocatalyst with a Graphitic Carbon Nitride Photocatalyst for Visible-Light Water Oxidation”, ChemPhotoChem, 4, 5175-5180 (2020)

K. Aratsu, R. Takeya, B. R. Pauw, M. J. Hollamby, Y. Kitamoto, N. Shimizu, H. Takagi, R. Haruki, S. Adachi, and S. Yagai, “Supramolecular copolymerization driven by integrative self-sorting of hydrogen-bonded rosettes”, Nature Comm., 11, 1623 (2020)

山下晃一, “W、Nbドープした光触媒BaTaO₂Nの電子状態に関する理論的研究”, 豊田研究報告, 74, 115 (2021)

K. Mishima, T. Sakai, K. Yokota, M. Taniguchi, Y. Aso, *Y. Ie, *K. Yamashita, “The Effect of a Two-Dimensional Structure on the Dielectric Constant and Photovoltaic Characteristics”, J. Photochemistry & Photobiology A: Chemistry, 401, 1122756(7 pages) (2020)

計画班C01

Ozaki, D.; Suzuki H.; Ogawa, K.; Sakamoto, R.; Inaguma,; Y.; Nakashima, K.; Tomita, O.; Kageyama, H.*; Abe, R.*, “Synthesis, band structure and photocatalytic properties of Sillén–Aurivillius oxychlorides BaBi₅Ti₃O₁₄Cl, Ba₂Bi₅Ti₄O₁₇Cl and Ba₃Bi₅Ti₅O₂₀Cl with triple-, quadruple- and quintuple-perovskite layers”, J. Mater. Chem. A, 13, 9, 8332-8340 (2021)

Nakada, A.; Kato, D.; Nelson, R.; Takahira, H.; Yabuuchi, M.; Higashi, M.; Suzuki, H.; Kirsanova, M.; Kakudou, N.; Tassel, C.; Yamamoto, T.; Brown, M. C.; Dronskowski, R.; Saeki, A.; Abakumov, A.; Kageyama, H.*, Abe, R.*, “Conduction Band Control of Oxyhalides with a Triple-Fluorite Layer for Visible Light Photocatalysis”, J. Am. Chem. Soc., 143, 6, 2491-2499 (2021)

Ozaki, D.; Suzuki, H.; Tomita, O.; Inaguma, Y.; Nakashima, K.; Kageyama, H.; Abe, R.*, “A new lead-free Sillén–Aurivillius oxychloride Bi₅SrTi₃O₁₄Cl with triple-perovskite layers for photocatalytic water splitting under visible light”, J. Photochem. Photobiol. A, 408, 113095 (2021)

Ogawa, K.; Wakisaka, Y.; Suzuki, H.; Tomita, O.; Abe, R.*, “Visible-Light-Responsive Oxyhalide PbBiO₂Cl Photoelectrode: On-Site Flux Synthesis on a Fluorine-Doped Tin Oxide Electrode”, ACS Appl. Mater. Interfaces., 13, 4, 5176-5183 (2020)

Kamata, R.; Kumagai, H.; Yamazaki, Y.; Higashi, M.; Abe, R.; Ishitani, O.*, “Durable Photoelectrochemical CO₂ Reduction with Water Oxidation using a Visible-Light Driven Molecular Photocathode”, J. Mater. Chem. A, 3, 9, 1517-1529 (2021)

Ozaki, D.; Suzuki H.; Nakada, A.; Higashi M.; Tomita, O.; Kageyama, H.*; Abe, R.*, “Triple-layered Sillén–Aurivillius Perovskite Oxychloride Bi₅PbTi₃O₁₄Cl as a Visible-light-responsive Photocatalyst for Water Splitting”, Chem. Lett., 49, 8, 978-981 (2020)

Ghosh, S.*; Nakada, A.; Springer, M.; Kawaguchi, T.; Suzuki, K.; Kaji, H.; Baburin, I.; Kuc, A.; Heine, T.; Suzuki, H.; Abe, R.*; Seki, S.*, “Identification of Prime Factors to Maximize the Photocatalytic Hydrogen Evolution of Covalent Organic Frameworks”, J. Am. Chem. Soc., 142, 21, 9752-9762 (2020)

Abin Sebastian, Sebastian Nybin Remello, Fazalurahman Kuttassery, Siby Mathew, Yutaka Ohsaki, Hiroshi Tachibana, Haruo Inoue*, “Protolytic behavior of water-soluble zinc(II) porphyrin and the　electrocatalytic two-electron water oxidation to form hydrogen peroxide”, J. Photochem. Photobiol. A, Chem., 400, 112619 (2020)

Yutaka Ohsaki, Arun Thomas, Fazalurahman Kuttassery, Siby Mathew, Sebastian Nybin Remello, Tetsuya Shimada, Tamao Ishida, Shinsuke Takagi, Hiroshi Tachibana, Haruo Inoue*, “Two-electron oxidation of water to form hydrogen peroxide initiated by one electron oxidation of Tin (IV)-porphyrins”, J. Photochem. Photobiol. A, Chem., 401, 112732 (2020)

Keito Sano, Fazalurahman Kuttassery, Tetsuya Shimada, Tamao Ishida, Shinsuke Takagi, Bunsho Ohtani, Akira Yamakata, Tetsuo Honma, Hiroshi Tachibana, and Haruo Inoue*, “Optically Transparent Colloidal Dispersion of Titania Nanoparticles　Storable for Longer than One Year Prepared by Sol/Gel Progressive　Hydrolysis/Condensation”, ACS Appl. Mater. Interfaces, 12, 44743−44753. (2020)

Sayuri Okunaka, Yugo Miseki, Kazuhiro Sayama, “Functions of MnOx in NaCl Aqueous Solution for Artificial Photosynthesis”, iScience, 23, 101540-101548 (2020)

Kojiro Fuku, Ryosuke Takioka, Kazushi Iwamura, Masanobu Todoroki, Kazuhiro Sayama, Naoki Ikenaga, “Photocatalytic H₂O₂production from O₂ under visible light irradiation over phosphate ion-coated Pd nanoparticles-supported BiVO₄”, Catalysis B: Environmental, 272, 119003-119010 (2020)

Yugo Miseki, Kana Fujita, Shoji Iguchi, Osamu Kitao, Takahiro Gunji and Kazuhiro Sayama, “In–Fe mixed oxide as an oxygen-evolution photocatalyst for visible-light-driven Z-scheme water splitting”, Sustainable Energy & Fuels, 4, 2686–2690 (2020)

Yuta Miyase, Yugo Miseki, Takahiro Gunji, Kazuhiro Sayama, “Efficient H₂O₂ Production via H₂O Oxidation on an Anode Modified with Sb‐Containing Mixed Metal Oxides”, ChemElectroChem, 7, 2448-2455 (2020)

Rui Pang, Yugo Miseki, Sayuri Okunaka, and Kazuhiro Sayama, “Photocatalytic Production of Hypochlorous Acid over Pt/WO₃ under Simulated Solar Light”, ACS Sustainable Chemistry & Engineering, 8, 8629–8637 (2020)

佐山和弘, “人工光合成による水素と有用化学品製造”, エネルギー・資源, 41, 180-184 (2020)

三石雄悟、佐山和弘, “経済合理性のある人工光合成実現に向けた取り組み”, 会報　光触媒, 61, 4-7 (2020)

三石雄悟、佐山和弘, “レドックス媒体を用いた様々なタイプの水分解反応”, 触媒（CatalystsandCatalysis）, 62, 242-246 (2020)

佐山和弘, “人工光合成による過酸化物製造”, 光アライアンス, 31, 20ー23 (2020)

Z. N. Zahran, E. A. Mohamed, Y. Tsubonouchi, M. Ishizaki, T. Togashi, M. Kurihara, K. Saito, T. Yui, M. Yagi, “Electrocatalytic water splitting with unprecedentedly low overpotentials”, Energy Environ. Sci., in press (2021)

Y. Tsubonouchi, D. Takahashi, M. R. Berber, E.　A. Mohamed, Z.　N. Zahran, A. M. Alenad, N. A. Althubiti, M. Yagi, “Highly selective electrocatalysis for carbon dioxide reduction to formic acid by a Co(II) complex with an equatorial N4 ligand”, Electrochim. Acta, 387, 4, 138545 (2021)

T. Eo, T. Katsuki, M. R. Berber, Z. N. Zahran, E. A. Mohamed, Y. Tsubonouchi, A. M. Alenad, N. A. Althubiti, M. Yagi, “Handy protocol of nitrogen-doped BiVO4 photoanode for visible light-driven water oxidation”, ACS Appl. Energy Mater, 4, 4, 2983-2989 (2021)

Z. N. Zahran, E. A. Mohamed, Y. Tsubonouchi, M. Ishizaki, T. Togashi, M. Kurihara, K. Saito, T. Yui, M. Yagi, “Concisely synthesized FeNiWOx film as a highly efficient and robust catalyst for electrochemical water oxidation”, ACS Appl. Energy Mater., 4, 2, 1410-1420 (2021)

Y. Tsubonouchi, Y. Tanahashi, T. Eo, J. Honta, T. Sato, E. A. Mohamed, Z. N. Zahran, K. Saito, T. Yui, M. Yagi, “High potential-applied catalyst behavior of a mononuclear ruthenium(II) complex on a mesoporous ITO electrode for water oxidation”, J. Electrochem. Soc., 16 , 166515 (2020)

Y. Tanahashi, S. Nagai, Y. Tsubonouchi, M. Hirahara, T. Sato, Z. N. Zahran, E. A. Mohamed, K. Saito, T. Yui, M. Yagi, “Efficient electrocatalytic water oxidation by a dinuclear ruthenium(II) complex with vicinal aquo and hydroxo groups adsorbed on TiO₂ electrode”, ACS Appl. Energy Mater., 3, 12, 12172-12184 (2020)

M. Hirahara, H. Goto, M. Yagi, Y. Umemura, “A multi-stimuli responsive ruthenium complex for catalytic water oxidation”, Chem. Commun., 56, 12825-12828 (2020)

M. Ishizaki, H. Tanno, H. Sutoh, T. Katsuki, T. Hayasaka, M. Yagi, Y. Tsubonouchi, K. Tajima, T. Kawamoto, Y. Sakuda, M. Kurihara, “FeNi layered double hydroxide nanoflakes with potential for intrinsically high water-oxidation catalytic activity”, ACS Appl. Energy Mater., 3, 9, 9040-9050 (2020)

Y. Tsubonouchi, T. Eo, J. Honta, T. Sato, E. A. Mohamed, Z. N. Zahran, K. Saito, T. Yui, M. Yagi, “Molecular aspects, electrochemical properties and water oxidation catalysis on a nanoporous TiO2 electrode anchoring a mononuclear ruthenium(II) aquo complex”, J. Photochem. Photobiol., A, 400, 112696-112700 (2020)

E. A. Mohamed, Z. N. Zahran, Y. Tsubonouchi, K. Saito, T. Yui, M. Yagi, “Highly efficient and selective electrocatalytic CO₂-to-CO conversion by a non-heme iron complex with an in-plane N4 ligand in heterogeneous aqueous media”, ACS Appl. Energy Mater, 3, 5, 4114-4120 (2020)

Y. Tsubonouchi, J. Honta, T. Sato, E. A. Mohamed, Z. N. Zahran, K. Saito, T. Yui, M. Yagi, “Multi-potential-step chronocoulospectrometry for electrocatalytic water oxidation by a mononuclear ruthenium aquo complex immobilized on a mesoporous ITO electrode”, Dalton Trans., 49, 5, 1416-1423 (2020)

計画班C02

S. Ho-Kimura, W. Soontornchaiyaku,Y. Yamaguchi, and A. Kudo*, “Preparation of Nanoparticle Porous-Structured BiVO₄ Photoanodes by a New Two-Step Electrochemical Deposition Method for Water Splitting”, Catalysts, 11, 136, (2021)

T. Shinoda, Y. Yamaguchi, A. Kudo, and N. Murakami*, “In situ photoacoustic analysis of near-infrared absorption of rhodium-doped strontium titanate photocatalyst powder”, Chem. Commun, 56, 14255-14258 (2020)

K. Watanabe, Y. Iikubo, Y. Yamaguchi, and A. Kudo*, “Highly crystalline Na_0.5Bi_0.5TiO₃ of a photocatalyst valence-bandcontrolled with Bi(III) for solar water splitting”, Chem. Commun, 57, 323-326 (2020)

K. Watanabe, K. Iwashina, A. Iwase, S. Nozawa, S. Adachi, and A. Kudo*, “New Visible-Light-Driven H₂- and O₂-Evolving Photocatalysts Developed by Ag(I) and Cu(I) Ion Exchange of Various Layered and Tunneling Metal Oxides Using Molten Salts Treatments”, Chem. Mater., 32, 24, 10524-10537 (2020)

S. Yoshino, K. Sato, Y. Yamaguchi, A. Iwase, and A. Kudo*, “Z-Schematic CO₂ Reduction to CO through Interparticle Electron Transfer between SrTiO₃:Rh of a Reducing Photocatalyst and BiVO₄ of a Water Oxidation Photocatalyst under Visible Light”, ACS Appl. Energy Mater, 3, 10001-10007 (2020)

Y. Bai, K. Nakagawa, A. J. Cowan, C. M. Aitchison, Y. Yamaguchi, M. A. Zwijnenburg, A. Kudo*, R. S. Sprick* and A. I. Cooper*, “Photocatalyst Z-scheme system composed of a linear conjugated polymer and BiVO₄ for overall water splitting under visible light”, J. Mater. Chem.A, 8, 16283-16290 (2020)

W. Kurashige, Y. Mori, S. Ozaki, M. Kawachi, S. Hossain, T. Kawawaki, C. J. Shearer, A. Iwase, G. F. Metha, S. Yamazoe, A. Kudo, and Y. Negishi*, “Activation of Water-Splitting Photocatalysts by Loading with Ultrafine Rh–Cr Mixed-Oxide Cocatalyst Nanoparticles”, Angewandte Chemie - International Edition, 59, 7076-7082 (2020)

S. Yoshino, A. Iwase, Y. H. Ng, R. Amal, and A. Kudo*, “Z-Schematic Solar Water Splitting Using Fine Particles of H₂-Evolving (CuGa)_0.5ZnS₂ Photocatalyst Prepared by a Flux Method with Chloride Salts”, ACS Appl. Energy Mater, 3, 5684-5692 (2020)

K.Vibulyaseak, A. Kudo, and M. Ogawa*, “Template Synthesis of Well-Defined Rutile Nanoparticles by Solid-State Reaction at Room Temperature”, Inorganic Chemistry, 59, 7934-7938 (2020)

S. Suzuki, A. Iwase and A. Kudo*, “Long wavelength visible light-responsive SrTiO₃ photocatalysts doped with valence-controlled Ru for sacrificial H₂ and O₂ evolution”, Catalysis Science & Technology, 10, 4912-4916 (2020)

山口友一，工藤昭彦, “金属イオン置換による可視光応答性光触媒の開発”, 触媒, 62, 213-216 (2020)

吉野隼矢，工藤昭彦, “粉末半導体光触媒および光電極系よる水を電子源としたCO₂還元”, エネルギー・資源, 41, 43-48 (2020)

工藤昭彦, “人工光合成とは”, エネルギー・資源, 41, 12-14 (2020)

David C. Fabry, Hiroki Koizumi, Debashis Ghosh, Yasuomi Yamazaki, Hiroyuki Takeda, Yusuke Tamaki and Osamu Ishitani, “A Ru(II) - Mn(I) Supermolecular Photocatalyst for CO₂ Reduction”, Organometallics, 39, 1511-1518 (2020)

Daiki Saito, Yasuomi Yamazaki, Yusuke Tamaki and Osamu Ishitani, “Photocatalysis of a Dinuclear Ru(II)-Re(I) Complex for CO₂ Reduction on a Solid Surface”, J. Am. Chem. Soc., 142, 45, 19249–19258 (2020)

Kohei Ozawa, Yusuke Tamaki, Kei Kamogawa, Kazuhide Koike, and Osamu Ishitani, “Factors Determining Formation Efficiencies of One-Electron-Reduced Species of Redox Photosensitizers”, J. Chem. Phys., 153, 154302 (2020)

Ryutaro Kamata, Hiromu Kumagai, Yasuomi Yamazaki, Masanobu Higashi, Ryu Abe, and Osamu Ishitani, “Durable Photoelectrochemical CO₂ Reduction with Water Oxidation using a Visible-Light Driven Molecular Photocathode”, J. Mater. Chem. A., 9, 1517 - 1529 (2021)

石谷　治, “二酸化炭素資源化を目指した人工光合成の重要性と現状”, 理論化学会誌「フロンティア」, 2, 2, 37-45 (2020)

Takayoshi Oshima, Shunta Nishioka,Yuta Kikuchi,Shota Hirai, Kei-ichi Yanagisawa, Miharu Eguchi, Yugo Miseki, Toshiyuki Yokoi, Tatsuto Yui, Koji Kimoto,Kazuhiko Sayama, Osamu Ishitani, Thomas Mallouk and Kazuhiko Maeda, “An Artificial Z-scheme Constructed from Dye-Sensitized Metal Oxide Nanosheets for Visible Light-Driven Overall Water Splitting”, J. Am. Chem. Soc., 142, 18, 8412-8420 (2020)

公募A班

Tani, K., Kanno, R., Makino, Y., Hall, M., Takenouchi, M., Imanishi, M., Yu, L.-J., Overmann, J., Madigan, M. T., Kimura, Y., Mizoguchi, A., Humbel, B. M. & Wang-Otomo, Z.-Y., “Cryo-EM structure of a Ca²⁺-bound photosynthetic LH1-RC complex containing multiple ab-polypeptides”, Nat. Commun., 11, 4955 (2020)

Seto, R., Takaichi, S., Kurihara, T., Kishi, R., Honda, M., Takenaka, S., Tsukatani, Y., Madigan, M. T., Overmann, J., Wang-Otomo, Z.-Y. & Kimura, Y., “Lycopene-family carotenoids confer thermostability on photocomplexes from a new thermophilic purple bacterium”, Biochemistry, 59, 2351 (2020)

Kangur, L., Räsep, M., Timpmann, K., Wang-Otomo, Z.-Y. & Freiberg, A., “The two light-harvesting membrane chromoproteins of Thermochromatium tepidum expose distinct robustness against temperature and pressure”, Biochim. Biophys. Acta –Bioenergetics, 1861, 148205 (2020)

Akita F*, Nagao R, Kato K, Nakajima Y, Yokono M, Ueno Y, Suzuki T, Dohmae N, Shen J-R*, Akimoto N*, Miyazaki N*, “Structure of a cyanobacterial photosystem I surrounded by octadecameric IsiA antenna proteins”, Commun Biol, 3, 232 (2020)

Nagao R, Kato K, Ifuku K, Suzuki T, Kamazawa M, Uchiyama I, Kashino Y, Dohmae N, Akimoto S, Shen J-R, Miyazaki N*, Akita F*, “Structural basis for assembly and function of a diatom photosystem I-light harvesting supercomplex”, Nature Commun, 11, 2481 (2020)

Kato K, Miyazaki N, Hamatuchi T, Nakajima Y, Akita F*, Yonekura K*, Shen J-R*, “High-resolution cryo-EM structure of photosystem II reveals damage from high-dose electron beams”, Commun Biol, 4, 1, 382 (2021)

*S. Yamasaki S, *M. Shoji, M. Kayanuma, V. Sladek, D. K. Inaoka,Y. Matsuo,T. Shiba, L. Young, A. L. Moore, K. Kita, Y. Shigeta, “Weak O₂ binding and strong H₂O₂ binding at the non-heme diiron center of Trypanosome Alternative Oxidase”, Biochimica et Biophysica Acta - Bioenergetics, 1862, 148356-9 (2021)

*M. Shoji, T. Murakawa, M. Boero, Y. Shigeta, H. Hayashi, T. Okajima, “Unique Protonation State of Aspartate and Topaquinone in the Active Site of Copper Amine Oxidase”, RSC Advances, 10, 38631-38639 (2020)

*K. Mishima, *M. Shoji, Y. Umena, M. Boero, Y. Shigeta, “Role of the Propionic Acid Side-Chain of C-Phycocyanin Chromophores in the Excited States for the Photosynthesis Process”, 93, 12, 1509-1519 (2020)

*M. Shoji, Y. Abe, M. Boero, Y. Shigeta , Y. Nishiya, “Reaction Mechanism of Monomeric Sarcosine Oxidase with N-Cyclopropylglycine”, Physical Chemistry Chemical Physics, 22, 16552-16561 (2020)

K. Miyagawa, S. Yamanaka, H. Isobe, M. Shoji, T. Kawakami, M. Taniguchi, M. Okumura and K. Yamaguchi, “Electronic and spin structures of CaMn₄Ox clusters in the S0 state of the oxygen evolving complex of photosystem II. Domain-based local pair natural orbital (DLPNO) coupled-cluster (CC) calculations using optimized geometries and natural orbitals (UNO) by”, Phys. Chem. Chem. Phys., 402, 27191-27205 (2020)

Hiroshi Kuroda, Keisuke Kawashima, Kazuyo Ueda, Takuya Ikeda, Keisuke Saito, Ryo Ninomiya, Chisato Hida, Yuichiro Takahashi and Hiroshi Ishikita*, “Proton transfer pathway from the oxygen-evolving complex in photosystem II substantiated by extensive mutagenesis”, Biochim Biophys Acta Bioenerg., 1862, 148329 (2020)

Masaki Tsujimura, Tomoyasu Noji, Keisuke Saito, Keiichi Kojima, Yuki Sudo and Hiroshi Ishikita*, “Mechanism of absorption wavelength shifts in anion channelrhodopsin-1 mutants”, Biochim Biophys Acta Bioenerg., 1862, 148349 (2020)

Masaki Tsujimura and Hiroshi Ishikita*, “Insights into the Protein Functions and Absorption Wavelengths of Microbial Rhodopsins”, J. Phys. Chem. B, 124, 11819-11826 (2020)

Manoj Mandal, Keisuke Saito and Hiroshi Ishikita*, “The Nature of the Short Oxygen-Oxygen Distance in the Mn₄CaO₆ Complex of Photosystem II Crystals”, J Phys Chem Lett., 11, 10262-10268 (2020)

Keisuke Saito, Manoj Mandal and Hiroshi Ishikita*, “Redox potentials along the redox-active low-barrier H-bonds in electron transfer pathways”, Phys Chem Chem Phys., 22, 25467-25473 (2020)

Keisuke Saito*, Komi Mitsuhashi and Hiroshi Ishikita*, “Dependence of the chlorophyll wavelength on the orientation of a charged group: Why does the accessory chlorophyll have a low site energy in photosystem II?”, J Photochem. Photobiol., 402, 112799 (2020)

Keichi Kojima, Natsuki Miyoshi, Atsushi Shibukawa, Srikanta Chowdhury, Masaki Tsujimura, Tomoyasu Noji, Hiroshi Ishikita, Akihiro Yamanaka and Yuki Sudo*, “Green-Sensitive, Long-Lived, Step-Functional Anion Channelrhodopsin-2 Variant as a High-Potential Neural Silencing Tool”, J Phys Chem Lett., 11, 6214-6218 (2020)

Keisuke Saito, Manoj Mandal and Hiroshi Ishikita*, “Energetics of Ionized Water Molecules in the H-Bond Network near the Ca²⁺ and Cl - Binding Sites in Photosystem II”, Biochemistry, 59, 3216-3224 (2020)

Keisuke Saito, Minesato Nakagawa and Hiroshi Ishikita*, “pKa of the ligand water molecules in the oxygen-evolving Mn₄CaO₅cluster in photosystem II”, Commun.Chem., 89, (2020)

Naoki Sakashita, Hiroshi Ishikita and Keisuke Saito*, “Rigidly hydrogen-bonded water molecules facilitate proton transfer in photosystem II”, Phys Chem Chem Phys., 22, 15831-15841 (2020)

Hiroyuki Tamura, Keisuke Saito and Hiroshi Ishikita*, “Acquirement of water-splitting ability and alteration of the charge-separation mechanism in photosynthetic reaction centers”, Proc Natl Acad Sci U S A., 117, 16373-16382 (2020)

Hiroyuki Tamura and Hiroshi Ishikita*, “Quenching of Singlet Oxygen by Carotenoids via Ultrafast Superexchange Dynamics”, J. Phys. Chem. A, 124, 5081-5088 (2020)

Trinh, M. D. L. , Miyazaki, D., Ono,S., Nomata, J., Kono,M.,Mino, H., Niwa, T., Okegawa,Y. , Motohashi, K., Taguchi,H.,Hisabori,T.,Masuda,S., “The evolutionary conserved iron-sulfur protein TCR controls P700 oxidation in photosystem I”, iScience, 24, 2, 102059 (2021)

Taguchi,S., Shen,L.,Han,G.,Umena, Y., Shen,J.-R., Noguchi,T.,Mino,H., “Formation of the High-Spin S2 State Related to the Extrinsic Proteins in the Oxygen Evolving Complex of Photosystem II”, J. Phys.Chem. Lett, 11, 8908-8913 (2020)

Taguchi,S., Noguchi,T.,Mino,H., “Molecular Structure of the S2 State with a g = 5 Signal in the Oxygen Evolving Complex of Photosystem II”, J. Phys.Chem. B, 124, 5531-5537 (2020)

Genki Kasagi, Yusuke Yoneda, Masaharu Kondo, Hiroshi Miyasaka, Yutaka Nagasawa, Takehisa Dewa, “Enhanced Light Harvesting and Photocurrent Generation Activities of Biohybrid Light–harvesting 1–Reaction Center Core Complexes (LH1-RCs) from Rhodopseudomonas palustris”, J. Photochem. Photobiol. A: Chemistry, 405, 112790 (2021)

Masaharu Kondo, Haruka Matsuda, Tomoyasu Noji, Mamoru Nango, and Takehisa Dewa, “Photocatalytic activity of the light-harvesting complex of photosystem II (LHCII) monomer”, J. Photochem. Photobiol. A: Chemistry, 405, 112926 (2021)

Wenchao Zhu, Raphaël Salles, Mariko Miyachi, Yoshinori Yamanoi, Tatsuya Tomo, Hiromi Takahashi, Hiroshi Nishihara, “Photoelectric Conversion System Composed of Gene-Recombined Photosystem I and Platinum Nanoparticle Nanosheet”, Langmuir, 36, 6429-6435 (2020)

Kousuke Kawahara, Natsuko Inoue-Kahino, Keisuke Namie, Yuki Kato, Tatsuya Tomo, Yutaka Shibata, Yasuhiro Kashino, Takumi Noguchi, “A gold nanoparticle conjugate with photosystem I and photosystem II for development of a biohybrid water-splitting photocatalyst", Biomedical Spectroscopy and Imaging, 73-81 (2020)

Asemgul K. Sadvakasova, Bekzhan D. Kossalbayev, Bolatkhan K. Zayadan, Kenzhegul Bolatkhan, Saleh Alwasel, Mohammad Mahdi Najafpour, Tatsuya Tomo, Suleyman I. Allakhverdiev, “Bioprocesses of hydrogen production by cyanobacteria cells and possible ways to increase their productivity", Renewable & Sustainable Energy Reviews, 133, 1100054 (2020)

Jimbo, H., Takagi, K., Hirashima, T., Nishiyama, Y. and Wada, H., “Long-chain saturated fatty acids, palmitic and stearic acids, enhance the repair of photosystem II”, International Journal of Molecular Sciences, 21, 20, 7509 (2020)

Izuhara, T., Kaihatsu, I., Jimbo, H., Takaichi, S. and Nishiyama, Y., “Elevated levels of specific carotenoids during acclimation to strong light protect the repair of photosystem II in Synechocystis sp. PCC 6803”, Frontiers in Plant Science, 11, 1030 (2020)

Yuasa, K., Shikata, T., Ichikawa, T., Tamura, Y. and Nishiyama, Y., “Nutrient deficiency stimulates the production of superoxide in the noxious red-tide-forming raphidophyte Chattonella antiqua”, Harmful Algae, 99, 101938 (2020)

Nishiyama, Y., “Resilience under climate change”, Nature Plants, 6, 442-443 (2020)

Yoshitaka Saga, Madoka Yamashita, Yuto Masaoka, Tsubasa Hidaka, Michie Imanishi, Yukihiro Kimura, and Yutaka Nagasawa, “Excitation Energy Transfer from Bacteriochlorophyll b in the B800 Site to B850 Bacteriochlorophyll a in Light-Harvesting Complex 2”, J. Phys. Chem. B, 125, 8, 2009–2017 (2021)

Rikako Kishi, Michie Imanishi, Masayuki Kobayashi, Shinji Takenaka, Michael T. Madigan, Zheng-Yu Wang-Otomo, Yukihiro Kimura, “Quinone transport in the closed light-harvesting 1 reaction center complex from the thermophilic purple bacterium Thermochromatium tepidum”, Biochimica et Biophysica Acta (BBA) - Bioenergetics, 1862, 1, 148307-148307 (2021)

Ryuta Seto, Shinichi Takaichi, Toshiyuki Kurihara, Rikako Kishi, Mai Honda, Shinji Takenaka, Yusuke Tsukatani, Michael T. Madigan, Zheng-Yu Wang-Otomo, Yukihiro Kimura, “Lycopene-Family Carotenoids Confer Thermostability on Photocomplexes from a New Thermophilic Purple Bacterium”, BIOCHEMISTRY, 59, 25, 2351-2358 (2020)

Kazutoshi Tani, Ryo Kanno, Yuki Makino, Malgorzata Hall, Mizuki Takenouchi, Michie Imanishi, Long-Jiang Yu, Jörg Overmann, Michael T. Madigan, Yukihiro Kimura, Akira Mizoguchi, Bruno M. Humbel, Zheng-Yu Wang-Otomo, “Cryo-EM structure of a Ca²⁺-bound photosynthetic LH1-RC complex containing multiple αβ-polypeptides”, Nature Communications, 11, 1, 4995 (2020)

Tasuku Hamaguchi, Keisuke Kawakami, Kyoko Shinzawa-Itoh, Natsuko Inoue-Kashino, Shigeru Itoh, Kentaro Ifuku, Eiki Yamashita, Kou Maeda, Koji Yonekura and Yasuhiro Kashino, “Structure of the far-red light utilizing photosystem I of Acaryochloris marina”, Nature Communications, 12, 2333 (2021)

公募B班

Kazumasa Oda, Takashi Nomura, Takanori Nakane, Keitaro Yamashita, Keiichi Inoue, Shota Ito, Johannes Vierock, Kunio Hirata, Andrés D Maturana, Kota Katayama, Tatsuya Ikuta, Itsuki Ishigami, Tamaki Izume, Rie Umeda, Ryuun Eguma, Satomi Oishi, Go Kasuya, Takafumi Kato, Tsukasa Kusakizako, Wataru Shihoya, Hiroto Shimada, Tomoyuki Takatsuji, Mizuki Takemoto, Reiya Taniguchi, Atsuhiro Tomita, Ryoki Nakamura, Masahiro Fukuda, Hirotake Miyauchi, Yongchan Lee, Eriko Nango, Rie Tanaka, Tomoyuki Tanaka, Michihiro Sugahara, Tetsunari Kimura, Tatsuro Shimamura, Takaaki Fujiwara, Yasuaki Yamanaka, Shigeki Owada, Yasumasa Joti, Kensuke Tono, Ryuichiro Ishitani, Shigehiko Hayashi, Hideki Kandori, Peter Hegemann, So Iwata, *Minoru Kubo, *Tomohiro Nishizawa, *Osamu Nureki, “Time-resolved serial femtosecond crystallography reveals early structural changes in channelrhodopsin”, eLife, 10, e62389 (2021)

Shoichi Tanimoto, Koichi Tamura, Shigehiko Hayashi, *Norio Yoshida, and Haruyuki Nakano, “A computational method to simulate global conformational changes of proteins induced by cosolvent”, Journal of Computational Chemistry, 42, 552-563 (2021)

Cheng Cheng and *Shigehiko Hayashi, “Ab Initio evaluation of the redox potential of cytochrome c”, Journal of Chemical Theory and Computation, 17, 2, 1194-1207 (2021)

Pedro Paulo Ferreira da Rosa, Shiori Miyazaki, Haruna Sakamoto, Yuichi Kitagawa, Kiyoshi Miyata, Tomoko Akama, Masato Kobayashi, Koji Fushimi, Ken Onda, Tetsuya Taketsugu, and Yasuchika Hasegawa, “Coordination geometrical effect on LMCT-depended energy transfer processes of luminescent Eu(III) complexes”, J Phys. Chem. A, 125, 209-217 (2021)

R. Fukaya, N. Yamaya, T. Ishikawa, S. Koshihara, K. Onda, Y. Okimoto, A. Isayama, T. Sasagawa, and K. Horigane, “Picosecond dynamics in layered cobalt perovskites studied by time-resolved Raman spectroscopy”, C. R. Phys., 22, 0, 1-8 (2021)

Shunsuke Sato, Sei'ichi Tanaka, Ken-ichi Yamanaka, Shu Saeki, Keita Sekizawa, Takeshi Morikawa, Ken Onda, “Study of excited states and electron transfer of semiconductor-metal complex hybrid photocatalysts for CO₂ reduction using picosecond time-resolved spectroscopies”, Chem. Eur. J., 27, 1127-1137 (2021)

Yuushi Shimoda, Kiyoshi Miyata, Masaki Saigo, Youichi Tsuchiya, Chihaya Adachi, Ken Onda, “Intramolecular-Rotation Driven Triplet-to-Singlet Upconversion and Fluctuation Induced Fluorescence Activation in Linearly-Connected Donor-Accepter Molecules”, J. Chem. Phys., 153, 204702 (2020)

Kenta Sasaki, Hitomi Yamate, Haruka Yoshino, Hiroki Miura, Kiyoshi Miyata, Ken Onda, Ryo Ohtani, and Masaaki Ohba, “Vapor Switching of Luminescence Mechanism in a Re(V) Complex”, Chem. Comm., 56, 12961-12964 (2020)

Shiori Miyazaki, Kiyoshi Miyata, Haruna Sakamoto, Fumiya Suzue, Yuichi Kitagawa, Yasuchika Hasegawa, Ken Onda, “Dual Energy Transfer Pathways from an Antenna Ligand to Lanthanide Ion in Trivalent Europium Complexes with Phosphine-Oxide Bridges”, J. Phys. Chem. A, 124, 6601-6606 (2020)

T. Shinoda, Y. Yamaguchi,A. Kudo, N. Murakami*, “In situ photoacoustic analysis of near-infrared absorption of rhodium-doped strontium titanate photocatalyst powder”, Chemical Communications, 56, 14255-14258 (2020)

N. Murakami*, R. Watanabe, “Simultaneous Measurements of Photoabsorption and Photoelectrochemical Performance for Thickness Optimization of a Semiconductor Photoelectrode”, ACS Combinatorial Science, 22, 791-795 (2020)

Chiasa Uragami, Hiroki Sato, Nao Yukihira, Masazumi Fujiwara, Nao Yukihira, Daisuke Kosumi, Alastair T. Gardiner, Richard J. Cogdell, Hideki Hashimoto*, “Photoprotective mechanism in core antenna pigment-protein from a purple photosynthetic bacterum, Rhodospirillum rubrum”, Journal of Photochemistry and Photobiology A: Chemistry, 400, 112628/1-9 (2020)

Hayata Yamamoto, Mayuka Taomoto, Akitaka Itho, Daisuke Kosumi*, “Electron-transfer behaviors between photoexcited metal complex and methyl viologen in ionic nanospheres”, Journal of Photochemistry and Photobiology A: Chemistry, 401, 112771/1-6 (2020)

Risa Kojima, Hayata Yamamoto, Chihiro Azai, Chiasa Uragami, Hideki Hashimoto, Daisuke Kosumi, Hirozao Oh-oka*, “Energy transfer and primary charge separation upon selective femtosecond excitation at 810 nm in the reaction center from Heliobacterium modesticaldum”, Journal of Photochemistry and Photobiology A: Chemistry, 401, 112758/1-7 (2020)

Chihiro Azai*,Jiro Harada, Shogo Fujimoto, Shinji Masuda, Daisuke Kosumi, “Anaerobic energy dissipation by glycosylated carotenoids in the green sulfur bacterium Chlorobaculum tepidum”, Journal of Photochemistry and Photobiology A: Chemistry, 403, 112828/1-9 (2020)

Fumiya Kobayashi, Ryohei Akiyoshi, Daisuke Kosumi, Masaaki Nakamura, Leonard F. Lindoy, and Shinya Hayam*, “Solvent Vapor-Induced Polarity and Ferroelectricity Switchin”, Chemical Communications, 56, 10509-10512 (2020)

Chihiro Azai, Masato Ueno, Shogo Fujimoto, Takumi Inoue, Jiro Harada, Shinji Masuda, Daisuke Kosumi, “Ultrafaste Excitation Energy Transfer Dynamics of Carotenoids bound to Photosynthetic Reaction Centers from Green Sulfur Bacteria C. tepidum”, Carotenoid Science, 24, 66-67 (2020)

Daisuke Kosumi, Toshiyuki Kusumoto, and Hideki Hashimoto, “Control of an Intramolecular Charge Transfer Character of Artificial Short-Polyene Carotenoid”, Carotenoid Science, 24, 68-69 (2020)

山元颯太、垰本真有華、伊藤亮孝、小澄大輔, “ナノイオンキャリアによる人工光合成実現に向けた電子伝達系の構築とその伝達過程の解明”, 光物性研究会論文集, 31, 137-140 (2020)

野原大暉、加藤駿弥、芹川広樹、川上恵典、神谷信夫、小澄大輔, “シアノバクテリア光化学系I,IIにおけるカロテノイドからクロロフィルへのエネルギー伝達ダイナミクス”, 光物性研究会論文集, 31, 81-84 (2020)

木田雅俊、山元颯太、川上恵典、内田博子、村上明男、神谷信夫、小澄大輔, “渦鞭毛藻光合成アンテナにおける超高速エネルギー伝達ダイナミクス”, 光物性研究会論文集, 31, 145-148 (2020)

Genki Kasagi, Yusuke Yoneda, Masaharu Kondo, Hiroshi Miyasaka, Yutaka Nagasawa, Takehisa Dewa, “Enhanced light harvesting and photocurrent generation activities of biohybrid light–harvesting 1–Reaction center core complexes (LH1-RCs) from Rhodopseudomonas palustris”, J. Photochem. Photobio. A: Chem., 405, 112790 (2021)

Yoshitaka Saga, Madoka Yamashita, Yuto Masaoka, Tsubasa Hidaka, Michie Imanishi, Yukihiro Kimura, and Yutaka Nagasawa, “Excitation Energy Transfer from Bacteriochlorophyll b in the B800 Site to B850 Bacteriochlorophyll a in Light-Harvesting Complex 2”, J. Phys. Chem. B, 125, 8, 2009–2017 (2021)

Yusuke Yoneda, Daiji Kato, Masaharu Kondo, Kenji V. P. Nagashima, Hiroshi Miyasaka, Yutaka Nagasawa, Takehisa Dewa, “Sequential energy transfer driven by monoexponential dynamics in a biohybrid light-harvesting complex 2 (LH2)”, Photosynth. Res., 143, 115–128 (2020)

Yoshitaka Saga, Yuji Otsuka, Daichi Funakoshi, Yuto Masaoka, Yu Kihara, Tsubasa Hidaka, Hiroka Hatano, Hitoshi Asakawa, Yutaka Nagasawa & Hitoshi Tamiaki, “In situ formation of photoactive B-ring reduced chlorophyll isomer in photosynthetic protein LH2”, Scientific Reports, 10, 19383 (2020)

Eisuke Takeuchi, Masayasu Muramatsu, Yusuke Yoneda, Tetsuro Katayama, Akira Iwamoto, Yutaka Nagasawa, and Hiroshi Miyasaka, “Vibrational decoherence induced by ultrafast intramolecular charge separation of an asymmetric bianthryl derivative”, J. Chem. Phys., 153, 84307 (2020)

Yosuke Takahashi, Keita Sugihara, Yutaka Nagasawa, “Excited State dynamics of charge transfer complexes of fullerenes in an electron donating solvent”, J. Photochem. Photobio. A: Chem., 403, 112861 (2020)

Keiji Naka, Hirofumi Sato and *Masahiro Higashi, “Theoretical study of the mechanism of the solvent dependency of ESIPT in HBT”, Phys. Chem. Chem. Phys., 23, 20080-20085 (2021)

公募C班

N. Yoshimura, *A. Kobayashi, M. Yoshida, *M. Kato, “Enhancement of Photocatalytic Activity for Hydrogen Production by Surface Modification of Pt-TiO₂ Nanoparticles with a Double Layer of Photosensitizers”, Chem. Eur. J., 26, 16939-16946 (2020)

N. Yoshimura, *A. Kobayashi, W. Genno, T. Okubo, M. Yoshida, *M. Kato, “Photosensitizing Ruthenium(II)-Dye Multilayers: Photoinduced Charge Separation and Back Electron Transfer Suppression”, Sustainable Energy&Fuels, 4, 3450-3457 (2020)

K. Nakamura, T. Oshikiri, K. Ueno, H. Ohta, H. Misawa, “Hot-carrier Separation Induced by the Electric Field of a p-n Junction between Titanium Dioxide and Nickel Oxide”, Chem. Lett., 50, 374-377 (2021)

Y. Cao, X. Shi, T. Oshikiri, S. Zu, Y. Sunaba, K. Sasaki, H. Misawa, “Near-field engineering for boosting the photoelectrochemical activity to a modal strong coupling structure”, Chem. Commun., 57, 524-527 (2021)

Y. Wang, X. Shi, T. Oshikiri, S. Zu, K. Ueno, H. Misawa, “Plasmon-induced electron injection into the large negative potential conduction band of Ga₂O₃ for coupling with water oxidation”, Nanoscale, 12, 22674-22679 (2020)

Tomoya Oshikiri, Xu Shi, Hiroaki Misawa, “Enhancement of selective fixation of dinitrogen to ammonia under modal strong coupling conditions”, Eur. J. Inorg. Chem., 2020, 1396-1401 (2020)

Daiki Sato ,Hiro Minamimoto , and *Kei Murakoshi, “Plasmon-induced Hydrogen Evolution Reaction on p-Type Semiconductor Electrode with Ag Nanodimer Structures”, Chemistry letter, 49, 7, 806－808 (2020)

Hiro Minamimoto, Fumiya Kato, *Kei Murakoshi, “Surface-enhanced Raman scattering probe for molecules strongly coupled with localized surface plasmon under electrochemical potential control”, Journal of Raman Spectroscopy, 52, 2, 431-438 (2021)

Hiro Minamimoto, Takahiro Toda, *Kei Murakoshi, “Spatial distribution of active sites for plasmon-induced chemical reactions triggered by well-defined plasmon modes”, Nanoscale, 13, 1784-1790 (2021)

Yuchun Wang, Hiro Minamimoto, Ruifeng Zhou, *Kei Murakoshi, “In Situ Monitoring of Electronic Structure in a Modal Strong Coupling Electrode under Enhanced Plasmonic Water Oxidation”, Journal of Physical Chemistry C, 125, 3, 1754-1760 (2021)

H. Kumagai, R. Aoyagi, K. Kato, A. Yamakata, M. Kakihana, H. Kato, “Utilization of perovskite-type oxynitride La_0.5Sr_0.5Ta_0.5Ti_0.5O₂N as an O₂-evolving photocatalyst in Z-scheme water splitting”, ACS Appl. Energy Mater., 4, 3, 2056-2060 (2021)

Takashi Yatsui, Felix Brandenburg, Benjamin Leuschel, and Olivier Soppera, “Synthesis of silver nanostructure on gold nanoparticle using near field assisted second harmonic generation”, Scientific Reports, 11, 5642 (2021)

*T. Yatsui, Y. Nakamura, Y. Suzuki, T. Morimoto, Y. Kato, M. Yamamoto, T. Yoshida, W. Kurashige, N. Shimizu, Y. Negishi, K. Iida, K. Nobusada, “Increase in CO₂ reduction rate via optical near-field effect”, J. Nonophotonics, 14, 4, 4011, (2020)

Saqura Ishino, Soutaro Shimada, Hiroshi Masai, Jun Terao, “Change in the Rate of pseudo[1]rotaxane Formation by Elongating the Alkyl-chain-substituted Diphenylethynylene Linked to Permethyl α-cyclodextrin”, Tetrahedron Lett., 61, 152061 (2020)

Hiromichi V. Miyagishi, Hiroshi Masai, Jun Terao, “Suppression of Undesirable Isomerization and Intermolecular Reactions of Double Bonds by a Linked Rotaxane Structure”, Chem. Asian J., 15, 1890-1895 (2020)

Masai H., Yokoyama T., Miyagishi H.V., Liu M., Tachibana Y., Fujihara T., Tsuji Y., Terao J., “Insulated conjugated bimetallopolymer with sigmoidal response by dual self-controlling system as a biomimetic material”, Nature Communications, 11, 1, 408 (2020)

Tamaki T., Minode K., Numai Y., Ohto T., Yamada R., Masai H., Tada H., Terao J., “Mechanical switching of current-voltage characteristics in spiropyran single-molecule junctions”, Nanoscale, 12, 14, 7527 (2020)

Sawada K., Tanaka T., Yokoyama T., Yamachi R., Oka Y., Chiba Y., Masai H., Terao J., Uchida K., “Co-porphyrin functionalized CVD graphene ammonia sensor with high selectivity to disturbing gases: Hydrogen and humidity”, Japanese Journal of Applied Physics, 59, 0, SGGG09 (2020)

Inamori D., Masai H., Tamaki T., Terao J., “Macroscopic Change in Luminescent Color by Thermally Driven Sliding Motion in [3]Rotaxanes”, Chemistry - A European Journal, 26, 15, 3385 (2020)

Masai H., Liu M., Tachibana Y., Tsuda S., Terao J., “Synthesis of Insulated Heteroaromatic Platinum-Acetylide Complexes with Color-Tunable Phosphorescence in Solution and Solid States”, Journal of Organic Chemistry, 85, 5, 3082 (2020)

Kaneko S., Masai H., Yokoyama T., Liu M., Tachibana Y., Fujihara T., Tsuji Y., Terao J., “Complementary color tuning by HC1 via phosphorescence-to-fluorescence conversion on insulated metallopolymer film and its light-induced acceleration”, Polymers, 12, 1, 244 (2020)

Taiki Kuwahara, Hideki Ohtsu, Kiyoshi Tsuge, “Synthesis and Photophysical Properties of Emissive Silver(I) Halogenido Coordination Polymers Composed of {Ag₂X₂} Units Bridged by Pyrazine, Methylpyrazine, and Aminopyrazine”, Inorg. Chem., 60, 3, 1299 (2021)

Yasuhiro Shiraishi, Takumi Hagi, Masako Matsumoto, Shunsuke Tanaka, Satoshi Ichikawa, and Takayuki Hirai, “Solar-to-Hydrogen Peroxide Energy Conversion on Resorcinol-Formaldehyde Resin Photocatalysts Prepared by Acid-catalyzed Polycondensation”, Communications Chemistry, 3, 169 (2020)

Yasuhiro Shiraishi, Yuki Ueda, Airu Soramoto, Satoshi Hinokuma, and Takayuki Hirai, “Photocatalytic Hydorogen Peroxide Splitting on Metal-Free Powders assisted by Phosphoric Acid as a Stabilizer”, Nature Communications, 11, 3386 (2020)

Natsumi Yano, Makoto Handa, Yusuke Kataoka, “Photophysical properties and Photosensitizing Abilities for Hydrogen Evolution Reactions of Robust Cyclometalated Iridium(III) Complexes with 5,5'-bis(trifluoromethyl)-2,2'-bipyridine”, Journal of Photochemistry and Photobiology A: Chemistry, 400, 1, 112716 (2020)

Wasusate Soontornchaiyakul, Takuya Fujimura, Natsumi Yano, Yusuke Kataoka, Ryo Sasai, “Photocatalytic Hydrogen Evolution over Exfoliated Rh Doped-Titanate Nanosheets”, ACS Omega, 5, 17, 9929-9936 (2020)

Satoshi Inoue, Yin-Nan Yan, Katsunori Yamanishi, Yusuke Kataoka, Tatsuya Kawamoto, “Photocatalytic and electrocatalytic hydrogen production using nickel complexes supported by hemilabile and non-innocent ligands”, Chemical Communications, 56, 19, 2829-2832 (2020)

Mari Yamane, Hiroyasu Tabe, Masami Kawakami, Hisashi Tanaka, Tohru Kawamoto, Yusuke Yamada, “Single Open Sites on FeII Ions Stabilized by Coupled Metal Ions in CN-Deficient Prussian Blue Analogues for High Catalytic Activity in the Hydrolysis of Organophosphates”,Inorg. Chem., 59, 21, 16000 (2020)

Gentaro Sakamoto, Hiroyasu Tabe, Yusuke Yamada, “Immobilization of Ir(OH)₃ Nanoparticles in Mesospaces of Al-SiO₂ Nanoparticles Assembly to Enhance Stability for Photocatalytic Water Oxidation”, Catalysis, 10, 9, 1015 (2020)

Hiroyasu Tabe, Akira Kitase, Yusuke Yamada, “Utilization of core-shell nanoparticles to evaluate subsurface contribution to water oxidation catalysis of [CoII(H₂O)₂]_1.5[Co^III(CN)₆] nanoparticles", Appl. Catal. B, 262, 118101 (2020)

Nobuto Yoshinari, Natthaya Meundaeng, Hiroyasu Tabe, Yusuke Yamada, Satoshi Yamashita, Yasuhiro Nakazawa, Takumi Konno, “Single-Crystal-to-Single-Crystal Installation of Ln₄(OH)₄ Cubanes in an Anionic Metallosupramolecular Framework ", Angewandte Chemie International Edition, 59, 41, 18048-18053 (2020)

Yutaka Amao, “Catalytic mechanism for selective hydrogen production based on formate decomposition with polyvinylpyrrolidone-dispersed platinum nanoparticles”, Sustainable Energy & Fuels, 4, 7, 3458-3466 (2020)

Ryohei Sato, Yutaka Amao, “Can formate dehydrogenase from Candida boidinii catalytically reduce carbon dioxide, bicarbonate, or carbonate to formate?”, New Journal of Chemistry, 44, 28, 11922-11926 (2020)

Yusuke Minami, Yutaka Amao, “Enhancement of catalytic activity for selective hydrogen production from formate with homogeneously poly(vinylpyrrolidone)/cationic poly(l-lysine) dispersed platinum nanoparticles”, New Journal of Chemistry, 44, 34, 14334-14338 (2020)

Akimitsu Miyaji, Yutaka Amao, “How does methylviologen cation radical supply two electrons to the formate dehydrogenase in the catalytic reduction process of CO₂to formate?”, Physical Chemistry Chemical Physics, 22, 33, 18595-18605 (2020)

Takayuki Katagiri, Yutaka Amao, “Trivalent metal ions promote the malic enzyme-catalyzed building of carbon–carbon bonds from CO₂ and pyruvate”, New Journal of Chemistry, 44, 40, 17208-17214 (2020)

Takayuki Katagiri, Yutaka Amao, “Recent advances in light-driven C–H bond activation and building C–C bonds with CO₂ as a feedstock for carbon capture and utilization technology”, Green Chemistry, 22, 20, 6682-6713 (2020)

Akimitsu Miyaji, Yutaka Amao, “Artificial co-enzyme based on carbamoyl-modified viologen derivative cation radical for formate dehydrogenase in the catalytic CO₂ reduction to formate”, New Journal of Chemistry, 44, 43, 18803-18812 (2020)

Akimitsu Miyaji, Yutaka Amao, “Theoretical study on CO₂ reduction catalyzed by formate dehydrogenase using the cation radical of a bipyridinium salt with an ionic substituent as a co-enzyme”, Physical Chemistry Chemical Physics, 22, 46, 26987-16994 (2020)

Francesco Secundo, Yutaka Amao, “Visible-light-driven CO₂ reduction to formate with a system of water-soluble zinc porphyrin and formate dehydrogenase in ionic liquid/aqueous media”, RSC Advances, 10, 69, 42354-42362 (2020)

Hayata Yamamoto, Mayuka Taomoto, Akitaka Ito, Daisuke Kosumi, “Electron-Transfer Behaviors between Photoexcited Metal Complex and Methyl Viologen Codoped in Ionic Nanospheres”, Journal of Photochemistry and Photobiology A: Chemistry, 401, 112771 (2020)

A. Ebina, S. Hossain, H. Horihata, S. Ozaki, S. Kato, T. Kawawaki, *Y. Negishi, “One-, Two-, and Three-Dimensional Self-Assembly of Atomically Precise Metal Nanoclusters”, Nanomaterials, 10, 1105, (2020)

K. Isozaki, T. Taguchi, K. Ishibashi, T. Shimoaka, W. Kurashige, Y. Negishi, T. Hasegawa, M. Nakamura, *K. Miki, “Mechanistic Study of Silane Alcoholysis Reaction with Self-Assembled Monolayer-Functionalized Gold Nanoparticle Catalysts”, Catalysts, 10, 908, (2020)

T. Kawawaki, Y. Mori, K. Wakamatsu, S. Ozaki, M. Kawachi, S. Hossain, *Y. Negishi, “Controlled Colloidal Metal Nanoparticles and Nanoclusters: Recent Applications as Cocatalysts for Improving Photocatalytic Water-splitting Activity”, J. Mater. Chem. A, 8, 16081-16113 (2020)

S. Hossain, D. Suzuki, T. Iwasa, R. Kaneko, T. Suzuki, S. Miyajima, Y. Iwamatsu, S. Pollitt, T. Kawawaki, N. Barrabés, G. Rupprechter, *Y. Negishi, “Determining and Controlling Cu-Substitution Sites in Thiolate-Protected Gold-Based 25-Atom Alloy Nanoclusters”, J. Phys. Chem. C, 124, 22304-22313 (2020)

*T. Yatsui, Y. Nakamura, Y. Suzuki, T. Morimoto, Y. Kato, M. Yamamoto, T. Yoshida, W. Kurashige, N. Shimizu, Y. Negishi, K. Iida, K. Nobusada, “Increase in CO₂ reduction rate via optical near-field effect”, J. Nonophotonics, 14, 46011, (2020)

*T. Hara, *M. Saeki, Y. Negishi, T. Kaji, C. Yamamoto, “Cell Density-Dependent Accumulation of Low Polarity Gold Nanocluster in Cultured Vascular Endothelial Cells”, J. Toxicol., 45, 795-800 (2020)

T. Kawawaki, Y. Imai, D. Suzuki, S. Kato, I. Kobayashi, T. Suzuki, R. Kaneko, S. Hossain, *Y. Negishi, “Atomically Precise Alloy Nanoclusters”, Chem. Euro. J., 26, 16150-16193 (2020)

T. Kawawaki,Y. Kataoka, S. Ozaki, M. Kawachi, M. Hirata, *Y. Negishi, “Creation of Active Water-splitting Photocatalysts by Controlling Cocatalysts Using Atomically Precise Metal Nanoclusters”, Chem. Commun., 57, 417-440 (2020)

T. Matsuyama, J. Hirayama,Y. Fujiki, S. Kikkawa, W. Kurashige, H. Asakura, N. Kawamura, Y. Negishi, N. Nakatani, K. Hatada, F. Ota, *S. Yamazoe, “Effect of Ligand on Electronic State of Gold in Ligand-Protected Gold Clusters Elucidated by X-ray Absorption Spectroscopy”, J. Phys. Chem. C., 125, 5, 3143-3149 (2020)

*S. Sarkar, P. K. Maji, Y. Negishi, S. Dutta, T. N. Das, R. Pan, S. Sarkar, “Cu(II)-Based Nanofibrous Metallogel for Phenoxazinone Synthase-Like Activity”, ACS Appl. Nano Mater., 4, 1455-1466 (2020)

T. Kawawaki, Y. Kataoka, M. Hirata, Y. Iwamatsu, S. Hossain, *Y. Negishi, “Toward the Creation of High-performance Heterogeneous Catalysts by Controlled Ligand Desorption from Atomically Precise Metal Nanoclusters”, Nanoscale Horiz., 6, 409-448 (2020)

T. Kawawaki, A. Ebina, Y. Hosokawa, S. Ozaki, D. Suzuki, S. Hossain, *Y. Negishi, “Thiolate-Protected Metal Nanoclusters: Recent Development in Synthesis, Understanding of Reaction, and Application in Energy and Environmental Field”, Small, 17, 2202005328, (2020)

C. Azai, J. Harada, S. Fujimoto, S. Masuda, D. Kosumi, “Anaerobic energy dissipation by glycosylated carotenoids in the green sulfur bacterium Chlorobaculum tepidum”, Journal of Photochemistry and Photobiology A: Chemistry, 403, 112828 (2020)

R. Kojima, H. Yamamoto, C. Azai, C. Uragami, H. Hashimoto, D. Kosumi, H. Oh-oka, “Energy transfer and primary charge separation upon selective femtosecond excitation at 810 nm in the reaction center complex from Heliobacterium modesticaldum”, Journal of Photochemistry and Photobiology A: Chemistry, 401, 112758 (2020)

I. Abdellaoui, M. M. Islam, M. Remeika, S. Kanno, R. Okamoto, K. Tajima, Y.-H. Ng, C. Budich, T. Maeda, T. Wada, S. Ikeda, T. Sakurai, “Mechanism of incorporation of zirconium into BiVO₄ visible-light photocatalyst”, J. Phys. Chem. C, 125, 6, 3320 (2021)

D. Huang, K. Wang, L. Li, K. Feng, N. An, S. Ikeda, Y. Kuang, Y. H. Ng, F. Jiang, “3.17% efficient Cu₂ZnSnS₄-BiVO₄ integrated tandem cell for standalone overall solar water splitting”, Energy Environ. Sci., 14, 1480 (2021)

S. Ikeda, W. Fujita, R. Okamoto, Y. Nose, R. Katsube, K. Yoshino, T. Harada, “Preparation of a CuGaSe₂ single crystal and its photocathodic properties”, RSC Adv., 10, 40310 (2020)

K. Feng, D. Huang, L. Li, K. Wang, J. Li, T. Harada, S. Ikeda, “MoSx-CdS/Cu₂ZnSnS₄-based thin film photocathode for solar hydrogen evolution from water”, Appl. Catal. B: Environ., 268, 118438 (2020)

I. Abdellaoui, M. M. Islam, M. Remeika, H. Yui, T. Harada, T. Maeda, C. Budich, T. Wada, S. Ikeda, T. Sakurai, “Photocarrier recombination dynamics in BiVO₄ for visible light-driven water oxidation”, J. Phys. Chem. C, 124, 7, 3962 (2020)

Tomohiro Higashino, Yuma Kurumisawa, Abraham B. Alemayehu, Rune F. Einrem, Debashis Sahu, Daniel Packwood, Kosaku Kato, Akira Yamakata*, Abhik Ghosh*, Hiroshi Imahori*, “Heavy Metal Effects on the Photovoltaic Properties of Metallocorroles in Dye-Sensitized Solar Cells”, ACS Applied Energy Materials, 3, 12460–12467 (2020)

Keito Sano, Fazalurahman Kuttassery, Tetsuya Shimada, Tamao Ishida, Shinsuke Takagi, Bunsho Ohtani, Akira Yamakata, Tetsuo Honma, Hiroshi Tachibana, Haruo Inoue*, “Optically Transparent Colloidal Dispersion of Titania Nanoparticles Storable for Longer than One Year Prepared by Sol/Gel Progressive Hydrolysis/Condensation”, ACS Applied Materials & Interfaces, 12, 44743-44753 (2020)

Junzhe Jiang, Kosaku Kato, Hirotaka Fujimori, Akira Yamakata, Yoshihisa Sakata*, “Investigation on the highly active SrTiO3 photocatalyst toward overall H2O splitting by doping Na ion”, Journal of Catalysis, 390, 81-89 (2020)

Ya Tang, Kosaku Kato, Takayoshi Oshima, Hiroto Mogi, Akinobu Miyoshi, Kotaro Fujii, Kei-ichi Yanagisawa, Koji Kimoto, Akira Yamakata, Masatomo Yashima, Kazuhiko Maeda*, “Synthesis of Three-Layer Perovskite Oxynitride K2Ca2Ta3O9N·2H2O and Photocatalytic Activity for H2 Evolution under Visible Light”, Inorganic Chemistry, 59, 11122-11128 (2020)

Naruki Hayashi, Kosaku Kato, Akira Yamakata*, “Enhancement of photoelectrochemical activity of TiO2 electrode by particulate/dense double-layer formation”, Journal of Chemical Physics, 152, 241101 (2020)

Akinobu Miyoshi, Kosaku Kato, Toshiyuki Yokoi, Jan J. Wiesfeld, Kiyotaka Nakajima, Akira Yamakata, Kazuhiko Maeda*, “Nano vs. bulk rutile TiO2:N,F in Z-scheme overall water splitting under visible light”, Journal of Materials Chemistry A, 8, 11996-12002 (2020)

Peng Zhang, Yawen Tong, Yong Liu, Junie Jhon M. Vequizo, Hongwei Sun, Can Yang, Akira Yamakata, Fengtao Fan, Wei Lin, Xinchen Wang, Wonyong Choi*, “Heteroatom Dopants Promote Two‐Electron O2 Reduction for Photocatalytic Production of H2O2 on Polymeric Carbon Nitride”, Angewandte Chemie International Edition, 59, 16209-16217 (2020)

Kosaku Kato, Akira Yamakata*, “Defect-Induced Acceleration and Deceleration of Photocarrier Recombination in SrTiO3 Powders”, Journal of Physical Chemistry C, 124, 11057–11063 (2020)

Haruki Wakayama, Kosaku Kato, Kodai Kashihara, Tomoki Uchiyama, Akinobu Miyoshi, Hiroko Nakata, Daling Lu, Kengo Oka, Akira Yamakata, Yoshiharu Uchimoto, Kazuhiko Maeda*, “Activation of a Pt-loaded Pb2Ti2O5.4F1.2 photocatalyst by alkaline chloride treatment for improved H2 evolution under visible light”, Journal of Materials Chemistry A, 8, 9099-9108 (2020)

Tomoki Kanazawa, Kosaku Kato, Ryusei Yamaguchi, Tomoki Uchiyama, Daling Lu, Shunsuke Nozawa, Akira Yamakata*, Yoshiharu Uchimoto, Kazuhiko Maeda*, “Cobalt Aluminate Spinel as a Cocatalyst for Photocatalytic Oxidation of Water: Significant Hole-Trapping Effect”, ACS Catalysis, 10, 4960-4966 (2020)

Shanshan Chen, Junie Jhon M. Vequizo, Takashi Hisatomi, Mamiko Nakabayashi, Lihua Lin, Zheng Wang, Akira Yamakata, Naoya Shibata, Tsuyoshi Takata, Taro Yamada, Kazunari Domen*, “Efficient photocatalytic hydrogen evolution on single-crystalline metal selenide particles with suitable cocatalysts”, Chemical Science, 11, 6436-6441 (2020)

PAGE TOP

文部科学省科学研究費補助金　新学術領域研究領域番号：4906（平成29～33年度）

光合成分子機構の学理解明と時空間制御による革新的光ー物質変換系の創製

I⁴LEC : Innovations for Light-Energy Conversion

研究成果

原著論文　2020年度

計画班A01

計画班A02

計画班A03

計画班B01

計画班B02

計画班C01

計画班C02

公募A班

公募B班

公募C班

研究成果

原著論文 2020年度

計画班A01

計画班A02

計画班A03

計画班B01

計画班B02

計画班C01

計画班C02

公募A班

公募B班

公募C班

原著論文　2020年度